1. History and Etymology

Maria Goeppert Mayer. https://handwiki.org/wiki/index.php?curid=1934089

Upon working on the Manhattan Project, the German physicist Maria Goeppert Mayer became interested in the properties of nuclear fission products, such as decay energies and half-lives.^[1] In 1948, she published a body of experimental evidence for the occurrence of closed nuclear shells for nuclei with 50 or 82 protons or 50, 82, and 126 neutrons.^[2]

It had already been known that nuclei with 20 protons or neutrons were stable: that was evidenced by calculations by Hungarian-American physicist Eugene Wigner, one of her colleagues in the Manhattan Project.^[3] Two years later, in 1950, a new publication followed in which she attributed the shell closures at the magic numbers to spin-orbit coupling.^[4]

According to Steven Moszkowski (a student of Maria Goeppert Mayer), the term "magic number" was coined by Wigner: "Wigner too believed in the liquid drop model, but he recognized, from the work of Maria Mayer, the very strong evidence for the closed shells. It seemed a little like magic to him, and that is how the words 'Magic Numbers' were coined."^[5]

These magic numbers were the bedrock of the nuclear shell model, which Mayer developed in the following years together with Hans Jensen and culminated in their shared 1963 Nobel Prize in Physics.^[6]

2. Doubly Magic

Nuclei which have neutron number and proton (atomic) numbers each equal to one of the magic numbers are called "doubly magic", and are especially stable against decay.^[7] The known doubly magic isotopes are helium-4, helium-10, oxygen-16, calcium-40, calcium-48, nickel-48, nickel-56, nickel-78, tin-100, tin-132, and lead-208. However, only the first, third, fourth, and last of these doubly magic nuclides are completely stable, although calcium-48 is extremely long-lived and therefore naturally occurring, disintegrating only by a very inefficient double beta minus decay process. Double beta decay in general is so rare that several nuclides exist which are predicted to decay by this mechanism but in which no such decay has yet been observed. Even in nuclides whose double beta decay has been confirmed through observations, half lives usually exceed the age of the universe by orders of magnitude and emitted beta- or gamma radiation is for virtually all practical purposes irrelevant.

Doubly-magic effects may allow existence of stable isotopes which otherwise would not have been expected. An example is calcium-40, with 20 neutrons and 20 protons, which is the heaviest stable isotope made of the same number of protons and neutrons. Both calcium-48 and nickel-48 are doubly magic because calcium-48 has 20 protons and 28 neutrons while nickel-48 has 28 protons and 20 neutrons. Calcium-48 is very neutron-rich for such a relatively light element, but like calcium-40, it is stabilized by being doubly magic.

Magic number shell effects are seen in ordinary abundances of elements: helium-4 is among the most abundant (and stable) nuclei in the universe^[8] and lead-208 is the heaviest stable nuclide. Alpha decay (the emission of a He-4 nucleus - also known as an alpha particle - by a heavy element undergoing radioactive decay) is common in part due to the extraordinary stability of Helium-4 which makes this type of decay energetically favored in most heavy nuclei over neutron emission, proton emission or any type of cluster decay other than He-4 emission. The stability of He-4 also leads to the absence of stable isobars of mass number 5 and 8 - indeed all nuclides of those mass numbers decay within fractions of a second to produce alpha particles.

Magic effects can keep unstable nuclides from decaying as rapidly as would otherwise be expected. For example, the nuclides tin-100 and tin-132 are examples of doubly magic isotopes of tin that are unstable, and represent endpoints beyond which stability drops off rapidly. Nickel-48, discovered in 1999, is the most proton-rich doubly magic nuclide known.^[9] At the other extreme, nickel-78 is also doubly magic, with 28 protons and 50 neutrons, a ratio observed only in much heavier elements, apart from tritium with one proton and two neutrons (⁷⁸Ni: 28/50 = 0.56; ²³⁸U: 92/146 = 0.63).^[10]

In December 2006, hassium-270, with 108 protons and 162 neutrons, was discovered by an international team of scientists led by the Technical University of Munich, having a half-life of 9 seconds.^[11] Hassium-270 evidently forms part of an island of stability, and may even be doubly magic due to the deformed (American football- or rugby ball-like) shape of this nucleus.^[12][13]

Although Z = 92 and N = 164 are not magic numbers, the undiscovered neutron-rich nucleus uranium-256 may be doubly magic and spherical due to the difference in size between low- and high-angular momentum orbitals, which alters the shape of the nuclear potential.^[14]

3. Derivation

Magic numbers are typically obtained by empirical studies; if the form of the nuclear potential is known, then the Schrödinger equation can be solved for the motion of nucleons and energy levels determined. Nuclear shells are said to occur when the separation between energy levels is significantly greater than the local mean separation.

In the shell model for the nucleus, magic numbers are the numbers of nucleons at which a shell is filled. For instance, the magic number 8 occurs when the 1s_1/2, 1p_3/2, 1p_1/2 energy levels are filled, as there is a large energy gap between the 1p_1/2 and the next highest 1d_5/2 energy levels.

The atomic analog to nuclear magic numbers are those numbers of electrons leading to discontinuities in the ionization energy. These occur for the noble gases helium, neon, argon, krypton, xenon, radon and oganesson. Hence, the "atomic magic numbers" are 2, 10, 18, 36, 54, 86 and 118. As with the nuclear magic numbers, these are expected to be changed in the superheavy region due to spin–orbit coupling effects affecting subshell energy levels. Hence copernicium (112) and flerovium (114) are expected to be more inert than oganesson (118), and the next noble gas after these is expected to occur at element 172 rather than 168 (which would continue the pattern).

In 2010, an alternative explanation of magic numbers was given in terms of symmetry considerations. Based on the fractional extension of the standard rotation group, the ground state properties (including the magic numbers) for metallic clusters and nuclei were simultaneously determined analytically. A specific potential term is not necessary in this model.^[15][16]