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HandWiki. UV-Vis Absorption Spectroelectrochemistry. Encyclopedia. Available online: https://encyclopedia.pub/entry/32013 (accessed on 23 September 2026).
HandWiki. UV-Vis Absorption Spectroelectrochemistry. Encyclopedia. Available at: https://encyclopedia.pub/entry/32013. Accessed September 23, 2026.
HandWiki. "UV-Vis Absorption Spectroelectrochemistry" Encyclopedia, https://encyclopedia.pub/entry/32013 (accessed September 23, 2026).
HandWiki. (2022, October 31). UV-Vis Absorption Spectroelectrochemistry. In Encyclopedia. https://encyclopedia.pub/entry/32013
HandWiki. "UV-Vis Absorption Spectroelectrochemistry." Encyclopedia. Web. 31 October, 2022.
UV-Vis Absorption Spectroelectrochemistry
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Ultraviolet-visible (UV-Vis) absorption spectroelectrochemistry (SEC) is a multiresponse technique that analyzes the evolution of the absorption spectra in UV-Vis regions during an electrode process. This technique provides information from an electrochemical and spectroscopic point of view. In this way, it enables a better perception about the chemical system of interest. On one hand, molecular information related to the electronic levels of the molecules is obtained from the evolution of the spectra. On the other hand, kinetic and thermodynamic information of the processes is obtained from the electrochemical signal. UV-Vis absorption SEC allows qualitative analysis, through the characterization of the different present compounds, and quantitative analysis, by determining the concentration of the analytes of interest. Furthermore, it helps to determine different electrochemical parameters such as absorptivity coefficients, standard potentials, diffusion coefficients, electronic transfer rate constants, etc. Throughout history, reversible processes have been studied with colored reagents or electrolysis products. Nowadays, it is possible to study all kinds of electrochemical processes in the entire UV-Vis spectral range, even in the near infrared (NIR).

electrolysis spectroelectrochemistry electrochemical

References

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  2. Garoz Ruiz, Jesús; Heras Vidaurre, Aránzazu; Colina Santamaría, Álvaro. "Multipurpose Spectroelectrochemistry: Paving the Way for In Vivo Measurements". Tesis Doctoral, Universidad de Burgos. 
  3. Garoz‐Ruiz, Jesus; Perales‐Rondon, Juan V.; Heras, Aranzazu; Colina, Alvaro (August 2019). "Spectroelectrochemistry of Quantum Dots" (in en). Israel Journal of Chemistry 59 (8): 679–694. doi:10.1002/ijch.201900028. ISSN 0021-2148. https://onlinelibrary.wiley.com/doi/abs/10.1002/ijch.201900028. 
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  5. Hernández, Carla Navarro; García, Maria Begoña González; Santos, David Hernández; Heras, Maria Aranzazu; Colina, Alvaro; Fanjul-Bolado, Pablo (March 2016). "Aqueous UV–VIS spectroelectrochemical study of the voltammetric reduction of graphene oxide on screen-printed carbon electrodes" (in en). Electrochemistry Communications 64: 65–68. doi:10.1016/j.elecom.2016.01.017. https://linkinghub.elsevier.com/retrieve/pii/S1388248116300066. 
  6. Skoog, Douglas A. (2001). Principios de análisis instrumental. Holler, F. James., Nieman, Timothy A., Martín Gómez, María del Carmen. (5th ed.). Madrid: McGraw-Hill Interamericana. ISBN 84-481-2775-7. OCLC 48512564. https://www.worldcat.org/oclc/48512564. 
  7. León, L.; Mozo, J.D. (May 2018). "Designing spectroelectrochemical cells: A review" (in en). TrAC Trends in Analytical Chemistry 102: 147–169. doi:10.1016/j.trac.2018.02.002. https://linkinghub.elsevier.com/retrieve/pii/S0165993617303436. 
  8. Handbook of electrochemistry. Zoski, Cynthia G. (1st ed.). Amsterdam: Elsevier. 2007. ISBN 978-0-08-046930-0. OCLC 162129983. https://www.worldcat.org/oclc/162129983. 
  9. Kaim, Wolfgang; Fiedler, Jan (2009). "Spectroelectrochemistry: the best of two worlds" (in en). Chemical Society Reviews 38 (12): 3373. doi:10.1039/b504286k. ISSN 0306-0012. http://xlink.rsc.org/?DOI=b504286k. 
  10. Zhai, Yanling; Zhu, Zhijun; Zhou, Susan; Zhu, Chengzhou; Dong, Shaojun (2018). "Recent advances in spectroelectrochemistry" (in en). Nanoscale 10 (7): 3089–3111. doi:10.1039/C7NR07803J. ISSN 2040-3364. http://xlink.rsc.org/?DOI=C7NR07803J. 
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