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Expanded Graphite Containing Iron Nanoparticles
Expanded Graphite Containing Iron Nanoparticles
Caption

Iron(III) chloride hexahydrate (FeCl3.6H2O) has a low melting point (39°C) and in presence of graphite flakes the liquid salt spontaneously intercalates in the graphite sheets, thus generating a graphite intercalation compound (GIC). At higher temperatures, the graphite intercalation compound expands because of water evaporation and gaseous chlorine generation by the thermal decomposition of the anhydrous iron(III) salt. In particular, after dehydration, FeCl3 decomposes to form chlorine (Cl2) and iron(II) chloride (FeCl2), which in turn disproportionates to generate elemental iron (Fe) and FeCl3, up to a complete conversion of the salt to elemental iron. Since the resulting expanded graphite filaments contain elemental iron nanoparticles, this material shows ferromagnetic properties [1].

Information
Contributor:
Update Date:
29 Jan 2024
View Times:
313
Image Gallery:
Nanoparticles
Subject:
Nanoscience & Nanotechnology
Keywords
Iron(III) chlorideIntercalation compoundsIron nanoparticlesMagnetismExpanded graphite
Carotenuto, G. Expanded Graphite Containing Iron Nanoparticles. Encyclopedia. Available online: https://encyclopedia.pub/image/379 (accessed on 29 April 2025).
Carotenuto G. Expanded Graphite Containing Iron Nanoparticles. Encyclopedia. https://encyclopedia.pub/image/379. Published Jan 29, 2024. Accessed 29 April, 2025.
Carotenuto, Gianfranco. Expanded Graphite Containing Iron Nanoparticles. 2024. Encyclopedia. https://encyclopedia.pub/image/379.
Carotenuto, G. (2024). Expanded Graphite Containing Iron Nanoparticles. Encyclopedia. https://encyclopedia.pub/image/379
Carotenuto, Gianfranco. "Expanded Graphite Containing Iron Nanoparticles." Encyclopedia, 2024, https://encyclopedia.pub/image/379. Accessed 29 April, 2025.
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