bubbling-type (bubbling of the gas phase through a layer of the liquid located on a hole tray
[21,22,23][21][22][23] or in a vertical channel
[24,25][24][25].
-
Direct Contact Condensers (DCCs) have a variety of purposes. They can be used to heat the liquid for heat recovery. The hot liquid can be used to heat rooms, preheat raw materials, or melt solids such as ice. DCCs can be used to cool the gas to generate condensate. Condensate can be used to purge a reaction product, such as acids coabsorbed in the DCC, condense a particulate by converting it from a vapor to a liquid or solid, and grow particulate by condensing directly on the particulate surface to improve its capture or reclaim water in arid regions. Direct Contact Condensers also can reduce gas volume, suppress stack plumes, and lower energy requirements.
2.1. Type of Direct Contact Condensers
In direct-contact condensers, the gas and liquid come in direct contact. The cooling liquid is sprayed into the gas region to start a rapid condensation, which maximizes the thermal efficiency of condensers. The heat is transferred from a gas to a liquid, and the condensate temperature is the same as that of the cooling liquid leaving the condenser. The condensate cannot be reused as feed water if the cooling water is not pure and free from harmful impurities. The occurrence of the other gases strongly impacts the heat transfer rate and condensation efficiency. This process is one of the important issues investigated experimentally or numerically to determine overall efficiency and properly design Direct Contact Condensers. The general classification of condensers is presented in
Figure 1.
Figure 1. Classification of condensers.
In a parallel flow jet type condenser, the exhaust steam and cooling water find their entry at the top of the condenser and then flow downwards, and condensate and water are finally collected at the bottom (
Figure 2).
Figure 2. Parallel flow type condenser.
The steam and cooling water enter the condenser from opposite directions in a counter jet type condenser. Generally, the exhaust steam travels upward and meets the cooling water, which flows downwards. In this low-level jet-type condenser (counter jet type condenser), presented in
Figure 3, the exhaust steam enters slightly lower than in a parallel flow jet-type condenser, and the cooling water is supplied from the top of the condenser chamber (
Figure 3). The direction of the steam is upward, and the cooling water is downward. An air pump creates a vacuum and is placed on top of the condenser. The vacuum sucks the cooling water, and a hollow cone plate collects the falling water, which joins the second series of streams and meets the exhaust steam entering from below. The resulting condensate is delivered to the tank through a vertical pipe by the condensate pump. Another solution of counter jet type condensers is called barometric condenser and is presented in
Figure 4. In this type, the shell is placed at the height of about 10.363 m above the hot well; thus, there is no need to provide an extraction pump. Provision of providing injection pump is observed, where water under pressure is unavailable.
Figure 3. Low-level counter-flow jet type condenser.
Figure 4. High-level counter-flow jet type condenser.
In
Figure 4, the discharge pipe is connected to the bottom of the condenser shell. The exhaust steam enters the system in the lower part of the condenser, with the flow direction pointing upwards. Cooling water enters at the top and is collected by a punched cone plate. An air pump creates the vacuum on top of the shell. Steam and cooling water mix together and are carried through a discharge pipe to the tank. The difference between low and high-level jet condensers is that there is no pump between the tank and the discharge pipe in the high-level type.
The last type of jet condenser is an ejector flow jet type condenser (
Figure 5). Here the exhaust steam and cooling water mix in hollow truncated cones. Due to this decreased pressure, exhaust steam and associated air are drawn through the truncated cones, finally leading to the diverging cone. In the diverging cone, a portion of kinetic energy is converted into pressure energy which is more than the atmospheric, so that condensate consisting of condensed steam, cooling water, and the air is discharged into the hot well. The exhaust steam inlet is provided with a non-return valve which does not allow the water from the hot well to rush back to the engine in case of cooling water supply to the condenser.
Figure 5. Ejector-flow jet type condenser.
The cooling cycle makes use of a steam ejector condenser. The steam ejector condenser is classified into two types based on the mixing method in the primary nozzle exit
[7,26][7][26]. The first one is the constant pressure jet ejector (CPJE), and the other one is the constant area jet ejector (CAJE). The CPJE performs better than the CAJE due to better turbulent mixing
[7,27][7][27]. In addition to having no moving parts, the steam ejector condenser benefits from lower maintenance and capital cost than the compressor.
2.2. Water and Gas Separation
After the exhaust passes through the Direct Contact Condenser (DCC) for condensation, the condensate water from the DCC consists of a proportion of non-condensable gases such as CO
2, air, or other gases. The stream is passed through the separator or non-condensable gas removal system, which separates the water and the non-condensable gases. By this method, the separated CO
2 can be sent to the CCU unit for further utilization, or the separated air gases can be removed from the system. Gas separation from the DCC outlet stream can be carried out in various methods. The axial flow cyclone separator is the most commonly used gas-liquid separation method widely used in industries. Kou et al.
[28] simulated and experimentally proved gas-liquid separation using an axial flow cyclone separator. The experiment is conducted by passing the gas-liquid mixture stream into the cylindrical axial flow separator. A guide vane at the bottom of the cyclone separator produces centrifugal force in the fluid passing through it. Once the fluid passes into the separator, the centrifugal force created in the fluid separates the gas and liquid due to the density difference. While the liquid is collected at the bottom, the gas escapes through the top of the separator
[28,29][28][29]. Ji et al.
[29] experimentally proved that the efficiency of the cyclone separator could be improved by combining components to the cyclone separator. The combined cyclone separator includes components such as a steady flow element, leaf grind element, and folding plate element, which increases the efficiency of gas-liquid separation by more than 95%. Chemical looping is one of the methods of splitting the H
2O and CO
2 in the exhaust gas. The exhaust, which consists of H
2O and CO
2 undergoes a chemical reaction with the metal oxide used in chemical looping and produces different components. Farooqui et al.
[30] state the process of chemical looping with cerium oxide (CeO
2). The H
2O and CO
2 are pressurized, and the temperature is raised up to 500 °C by compression. By integrating chemical looping, oxidation occurs with CeO
2, which splits H
2O into Hydrogen and CO
2 into carbon monoxide. The separated components from the exhaust of the chemical looping is further used for dimethyl ether (DME) production. This is considered one of the methods for CCU technology using chemical looping. Wotzka et al.
[31] presented the possibility of separating CO
2 and water with the application of a microporous membrane. The separation of carbon dioxide and water using an MFI zeolite membrane treated with amine is analyzed experimentally and with molecular simulation. For experimental purposes, the liquid water is heated up to 120 °C, mixed with CO
2 in an evaporator, and further sent to separation. The performance of membrane separation is analyzed under different factors.