Application of PEDOT: Comparison
Please note this is a comparison between Version 2 by Bruce Ren and Version 1 by Nan Gao.

Poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) is a highly important and attractive conducting polymer as well as commercially available in organic electronics, including electrochemical and electronic chemosensors, due to its unique features such as excellent solution-fabrication capability and miscibility, high and controllable conductivity, excellent chemical and electrochemical stability, good optical transparency and biocompatibility.

  • PEDOT:PSS
  • chemosensor
  • electrochemistry
  • chemoresistive
  • organic electronics
Please wait, diff process is still running!

References

  1. Kumar, H.; Kumari, N.; Sharma, R. Nanocomposites (conducting polymer and nanoparticles) based electrochemical biosensor for the detection of environment pollutant: Its issues and challenges. Environ. Impact Assess. Rev. 2020, 85, 106438.
  2. Nezakati, T.; Seifalian, A.; Tan, A.; Seifalian, A.M. Conductive polymers: Opportunities and challenges in biomedical applications. Chem. Rev. 2018, 118, 6766–6843.
  3. Ramdzan, N.S.M.; Fen, Y.W.; Anas, N.A.A.; Omar, N.A.S.; Saleviter, S. Development of biopolymer and conducting polymer-based optical sensors for heavy metal ion detection. Molecules 2020, 25, 2548–2573.
  4. Wen, Y.P.; Xu, J.K. Scientific importance of water-processable PEDOT-PSS and preparation, challenge and new application in sensors of its film electrode: A review. J. Polym. Sci. Part A Polym. Chem. 2017, 55, 1121–1150.
  5. Dubey, N.; Kushwaha, C.S.; Shukla, S.K. A review on electrically conducting polymer bionanocomposites for biomedical and other applications. Int. J. Polym. Mater. Polym. Biomater. 2019, 69, 709–727.
  6. Zamiri, G.; Haseeb, A. Recent trends and developments in graphene/conducting polymer nanocomposites chemiresistive sensors. Materials 2020, 13, 3311.
  7. Bae, J.; Hwang, Y.; Park, S.-H.; Park, S.J.; Lee, J.; Kim, H.J.; Jang, A.; Park, S.; Kwon, O.S. An elaborate sensor system based on conducting polymer-oligosaccharides in hydrogel and the formation of inclusion complexes. J. Ind. Eng. Chem. 2020, 90, 266–273.
  8. Mantione, D.; Del Agua, I.; Sanchez-Sanchez, A.; Mecerreyes, D. Poly(3,4-ethylenedioxythiophene) (PEDOT) derivatives: Innovative conductive polymers for bioelectronics. Polymers 2017, 9, 354.
  9. Cho, K.H.; Yu, H.; Lee, J.S.; Jang, J. Facile synthesis of palladium-decorated three-dimensional conducting polymer nanofilm for highly sensitive H2 gas sensor. J. Mater. Sci. 2020, 55, 5156–5165.
  10. Morais, R.M.; Klem, M.d.S.; Nogueira, G.L.; Gomes, T.C.; Alves, N. Low cost humidity sensor based on PANI/PEDOT:PSS printed on paper. IEEE Sens. J. 2018, 18, 2647–2651.
  11. Tajik, S.; Beitollahi, H.; Nejad, F.G.; Shoaie, I.S.; Khalilzadeh, M.A.; Asl, M.S.; Van Le, Q.; Zhang, K.; Jang, H.W.; Shokouhimehr, M. Recent developments in conducting polymers: Applications for electrochemistry. RSC Adv. 2020, 10, 37834–37856.
  12. Hakimi, M.; Salehi, A.; Boroumand, F.A. Fabrication and characterization of an ammonia gas sensor based on PEDOT-PSS with n-doped graphene quantum dots dopant. IEEE Sens. J. 2016, 16, 6149–6154.
  13. Rahimzadeh, Z.; Naghib, S.M.; Zare, Y.; Rhee, K.Y. An overview on the synthesis and recent applications of conducting poly(3,4-ethylenedioxythiophene) (PEDOT) in industry and biomedicine. J. Mater. Sci. 2020, 55, 7575–7611.
  14. Elschner, A.; Kirchmeyer, S.; Lövenich, W.; Merker, U.; Reuter, K. PEDOT-Principles and Applications of an Intrinsically Conductive Polymer; CRC Press: New York, NY, USA, 2011.
  15. Zheng, Y.; Zeng, H.N.; Zhu, Q.; Xu, J.W. Recent advances in conducting poly(3,4-ethylenedioxythiophene):polystyrene sulfonate hybrids for thermoelectric applications. J. Mater. Chem. C 2018, 6, 8858–8873.
  16. Sun, K.; Zhang, S.P.; Li, P.C.; Xia, Y.J.; Zhang, X.; Du, D.H.; Isikgor, F.H.; Ouyang, J.Y. Review on application of PEDOTs and PEDOT:PSS in energy conversion and storage devices. J Mater. Sci. Mater Electron. 2015, 26, 4438–4462.
  17. Ouyang, J.Y. Recent advances of intrinsically conductive polymers. Acta Phys. Chim. Sin. 2018, 34, 1211–1220.
  18. Kaur, G.; Kaur, A.; Kaur, H. Review on nanomaterials/conducting polymer based nanocomposites for the development of biosensors and electrochemical sensors. Polym. Plast. Tech. Mat. 2020, 60, 502–519.
  19. Chen, Y.C.; O’Hare, D. Exhaled breath condensate based breath analyser-a disposable hydrogen peroxide sensor and smart analyser. Analyst 2020, 145, 3549–3556.
  20. Li, S.Y.; Chen, S.J.; Zhuo, B.G.; Li, Q.F.; Liu, W.J.; Guo, X.J. Flexible ammonia sensor based on PEDOT:PSS/silver nanowire composite film for meat freshness monitoring. IEEE Electr. Device L. 2017, 38, 975–978.
  21. Kayser, L.V.; Lipomi, D.J. Stretchable Conductive polymers and composites based on PEDOT and PEDOT: PSS. Adv. Mater. 2019, 31, 1806133.
  22. Reynolds, J.R.; Tompson, B.C.; Skotheim, T.A. Conjugated Polymers: Properties, Processing, and Applications; CRC Press: New York, NY, USA, 2019.
  23. Mariani, F.; Gualandi, I.; Tonelli, D.; Decataldo, F.; Possanzini, L.; Fraboni, B.; Scavetta, E. Design of an electrochemically gated organic semiconductor for pH sensing. Electrochem. Commun. 2020, 116, 106763–106770.
  24. Khodagholy, D.; Rivnay, J.; Sessolo, M.; Gurfinkel, M.; Leleux, P.; Jimison, L.H.; Stavrinidou, E.; Herve, T.; Sanaur, S.; Owens, R.M. High transconductance organic electrochemical transistors. Nat. Commun. 2013, 4, 2133.
  25. Liao, J.J.; Si, H.W.; Zhang, X.D.; Lin, S.W. Functional sensing interfaces of PEDOT: PSS organic electrochemical transistors for chemical and biological sensors: A mini review. Sensors 2019, 19, 218–233.
  26. Yan, Y.J.; Wu, X.M.; Chen, Q.Z.; Liu, Y.Q.; Chen, H.P.; Guo, T.L. High-performance low-voltage flexible photodetector arrays based on all-solid-state organic electrochemical transistors for photosensing and imaging. ACS Appl. Mater. Inter. 2019, 11, 20214–20224.
  27. Choosang, J.; Thavarungkul, P.; Kanatharana, P.; Numnuam, A. AuNPs/PpPD/PEDOT: PSS-Fc modified screen-printed carbon electrode label-free immunosensor for sensitive and selective determination of human serum albumin. Microchem. J. 2020, 155, 104709–104716.
  28. Abd-Wahab, F.; Abdul Guthoos, H.F.; Wan Salim, W.W.A. Solid-state rGO-PEDOT: PSS transducing material for cost-effective enzymatic sensing. Biosensors 2019, 9, 36–50.
  29. Bhasin, A.; Sanders, E.C.; Ziegler, J.M.; Briggs, J.S.; Drago, N.P.; Attar, A.M.; Santos, A.M.; True, M.Y.; Ogata, A.F.; Yoon, D.V.; et al. Virus bioresistor (VBR) for detection of bladder cancer marker DJ-1 in urine at 10 pM in one minute. Anal. Chem. 2020, 92, 6654–6666.
  30. El-Said, W.A.; Abdelshakour, M.; Choi, J.H.; Choi, J.W. Application of conducting polymer nanostructures to electrochemical biosensors. Molecules 2020, 25, 307–317.
  31. Amirzadeh, Z.; Javadpour, S.; Shariat, M.H.; Knibbe, R. Non-enzymatic glucose sensor based on copper oxide and multi-wall carbon nanotubes using PEDOT: PSS matrix. Synth. Met. 2018, 245, 160–166.
  32. Borras-Brull, M.; Blondeau, P.; Riu, J. The use of conducting polymers for enhanced electrochemical determination of hydrogen peroxide. Crit. Rev. Anal. Chem. 2020, 1–14.
  33. Zhang, R.L.; Xu, X.F.; Fan, X.X.; Yang, R.C.; Wu, T.; Zhang, C.G. Application of conducting micelles self-assembled from commercial poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) and chitosan for electrochemical biosensor. Colloid Polym. Sci. 2018, 296, 495–502.
  34. Słoniewska, A.; Kasztelan, M.; Berbeć, S.; Pałys, B. Influence of buffer solution on structure and electrochemical properties of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) hydrogels. Synth. Met. 2020, 263, 116363–116369.
  35. Xu, J.J.; Peng, R.; Ran, Q.; Xian, Y.Z.; Tian, Y.; Jin, L.T. A highly soluble poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonic acid)/Au nanocomposite for horseradish peroxidase immobilization and biosensing. Talanta 2010, 82, 1511–1515.
  36. Yao, Y.Y.; Wen, Y.P.; Zhang, L.; Xu, J.K.; Wang, Z.F.; Duan, X.M. A stable sandwich-type hydrogen peroxide sensor based on immobilizing horseradish peroxidase to a silver nanoparticle monolayer supported by PEDOT: PSS-nafion composite electrode. Int. J. Electrochem. Sci. 2013, 8, 9348–9359.
  37. Mercante, L.A.; Facure, M.H.M.; Sanfelice, R.C.; Migliorini, F.L.; Mattoso, L.H.C.; Correa, D.S. One-pot preparation of PEDOT: PSS-reduced graphene decorated with Au nanoparticles for enzymatic electrochemical sensing of H2O2. Appl. Surf. Sci. 2017, 407, 162–170.
  38. Siao, H.-W.; Chen, S.-M.; Lin, K.-C. Electrochemical study of PEDOT-PSS-MDB-modified electrode and its electrocatalytic sensing of hydrogen peroxide. J. Solid State Electr. 2010, 15, 1121–1128.
  39. Zahed, M.A.; Barman, S.C.; Das, P.S.; Sharifuzzaman, M.; Yoon, H.S.; Yoon, S.H.; Park, J.Y. Highly flexible and conductive poly (3, 4-ethylene dioxythiophene)-poly (styrene sulfonate) anchored 3-dimensional porous graphene network-based electrochemical biosensor for glucose and pH detection in human perspiration. Biosens. Bioelectron. 2020, 160, 112220–112229.
  40. Smith, R.E.; Totti, S.; Velliou, E.; Campagnolo, P.; Hingley-Wilson, S.M.; Ward, N.I.; Varcoe, J.R.; Crean, C. Development of a novel highly conductive and flexible cotton yarn for wearable pH sensor technology. Sens. Actuator B Chem. 2019, 287, 338–345.
  41. Naficy, S.; Oveissi, F.; Patrick, B.; Schindeler, A.; Dehghani, F. Printed, flexible pH sensor hydrogels for wet environments. Adv. Mater. Technol. US 2018, 3, 1800137–1800146.
  42. Reid, D.O.; Smith, R.E.; Garcia-Torres, J.; Watts, J.F.; Crean, C. Solvent treatment of wet-spun PEDOT:PSS fibers for fiber-based wearable pH sensing. Sensors 2019, 19, 4213–4222.
  43. Shi, H.; Liu, C.C.; Jiang, Q.L.; Xu, J.K. Effective approaches to improve the electrical conductivity of PEDOT:PSS: A review. Adv. Electron. Mater. 2015, 1, 1500017–1500032.
  44. Coppedè, N.; Giannetto, M.; Villani, M.; Lucchini, V.; Battista, E.; Careri, M.; Zappettini, A. Ion selective textile organic electrochemical transistor for wearable sweat monitoring. Org. Electron. 2020, 78, 105579–105584.
  45. Keene, S.T.; Fogarty, D.; Cooke, R.; Casadevall, C.D.; Salleo, A.; Parlak, O. Wearable organic electrochemical transistor patch for multiplexed sensing of calcium and ammonium ions from human perspiration. Adv. Healthc. Mater. 2019, 8, 1901321–1901328.
  46. Abd, E.A.; Mohamed, A.-O.; Ayman, H.K.; Elsayed, A.E. Single-piece solid contact Cu(2+)-selective electrodes based on a synthesized macrocyclic calix[4]arene derivative as a neutral carrier ionophore. Molecules 2019, 24, 920–931.
  47. Urbanowicz, M.; Pijanowska, D.G.; Jasiński, A.; Ekman, M.; Bocheńska, M.K. A miniaturized solid-contact potentiometric multisensor platform for determination of ionic profiles in human saliva. J. Solid State Electr. 2019, 23, 3299–3308.
  48. Ocana, C.; Munoz-Correas, M.; Abramova, N.; Bratov, A. Comparison of different commercial conducting materials as ion-to-electron transducer layers in low-cost selective solid-contact electrodes. Sensors 2020, 20, 1348–1359.
  49. Wagner, M.; Lisak, G.; Ivaska, A.; Bobacka, J. Durable PEDOT: PSS films obtained from modified water-based inks for electrochemical sensors. Sens. Actuator B Chem. 2013, 181, 694–701.
  50. Shadrina, A.A.; Nikiforova, T.G.; Poturai, D.O. Fabrication of electrodes modified with poly-3,4-ethylenedioxythiophene-polystyrene sulfonate film and study of their applicability in thiol-sensitive sensors. Russ. J. Appl. Chem. 2015, 88, 423–429.
  51. Yang, X.; Kirsch, J.; Olsen, E.V.; Fergus, J.W.; Simonian, A.L. Anti-fouling PEDOT: PSS modification on glassy carbon electrodes for continuous monitoring of tricresyl phosphate. Sens. Actuator B Chem. 2013, 177, 659–667.
  52. Chekol, F.; Mehretie, S.; Hailu, F.A.; Tolcha, T.; Megersa, N.; Admassie, S. Roll-to-roll printed PEDOT/PSS/GO plastic film for electrochemical determination of carbofuran. Electroanalysis 2019, 31, 1104–1111.
  53. Chai, J.D.; Zhang, J.; Wen, Y.P.; Zou, L.; Zhang, X.X.; Xin, X.; Zhou, M.H.; Xu, J.K.; Zhang, G. Highly sensitive electrochemical sensor based on PEDOT:PSS-β-CD-SWCNT-COOH modified glassy carbon electrode enables trace analysis shikonin. J. Electrochem. Soc. 2019, 166, B388–B394.
  54. Wong, A.; Santos, A.M.; Fatibello-Filho, O. Determination of piroxicam and nimesulide using an electrochemical sensor based on reduced graphene oxide and PEDOT: PSS. J. Electroanal. Chem. 2017, 799, 547–555.
  55. Tirawattanakoson, R.; Rattanarat, P.; Ngamrojanavanich, N.; Rodthongkum, N.; Chailapakul, O. Free radical scavenger screening of total antioxidant capacity in herb and beverage using graphene/PEDOT:PSS-modified electrochemical sensor. J. Electroanal. Chem. 2016, 767, 68–75.
  56. Zheng, L. An electrochemical sensor on the novel MgO-PEDOT: PSS platform for sensitive bisphenol a determination. Int. J. Electrochem. Sc. 2019, 14, 9030–9041.
  57. Wong, A.; Santos, A.M.; Silva, T.A.; Fatibello-Filho, O. Simultaneous determination of isoproterenol, acetaminophen, folic acid, propranolol and caffeine using a sensor platform based on carbon black, graphene oxide, copper nanoparticles and PEDOT:PSS. Talanta 2018, 183, 329–338.
  58. Manivannan, K.; Sivakumar, M.; Cheng, C.-C.; Lu, C.-H.; Chen, J.-K. An effective electrochemical detection of chlorogenic acid in real samples: Flower-like ZnO surface covered on PEDOT: PSS composites modified glassy carbon electrode. Sensor. Actuat. B-Chem. 2019, 301, 127002–127009.
  59. Pang, D.; Ma, C.; Chen, D.Z.; Shen, Y.L.; Zhu, W.Q.; Gao, J.J.; Song, H.O.; Zhang, X.M.; Zhang, S.P. Silver nanoparticle-functionalized poly (3, 4-ethylenedioxythiophene): Polystyrene film on glass substrate for electrochemical determination of nitrite. Org. Electron. 2019, 75, 105374–105380.
  60. Tian, Q.Y.; Xu, J.K.; Xu, Q.; Duan, X.M.; Jiang, F.X.; Lu, L.M.; Jia, H.Y.; Jia, Y.H.; Li, Y.Y.; Yu, Y.F. A poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)-based electrochemical sensor for tert.-butylhydroquinone. Mikrochim. Acta 2019, 186, 772–779.
  61. Zhang, H.; Xu, J.K.; Wen, Y.P.; Wang, Z.F.; Zhang, J.; Ding, W.C. Conducting poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) film electrode with superior long-term electrode stability in water and synergistically enhanced electrocatalytic ability for application in electrochemical sensors. Synth. Met. 2015, 204, 39–47.
  62. Zhang, J.; Xu, J.K.; Wen, Y.P.; Wang, Z.F.; Zhang, H.; Ding, W.C. Voltammetric determination of phytoinhibitor maleic hydrazide using PEDOT:PSS composite electrode. J. Electroanal. Chem. 2015, 751, 65–74.
More