1.3.1. Single Modification
Each type of waste plastic has its own chemical composition, unique structure, molecular weight, etc., all of which affect the performance of modified asphalt [
26] when such plastics are used as a modifier independently in asphalt production.
- (1)
-
Waste LDPE
LDPE has a lower specific gravity, strength, and temperature resistance than HDPE because of its long, flexible, and linear polyethylene chain [
65]. Due to the irregular structure of the multimolecular chain arrangement of LDPE, the branched chains in asphalt combine with each other to form reticular three-dimensional structures, which can better improve the properties of modified asphalt. Thus, LDPE is widely used as a modified material for asphalt. Since the 1990s, several studies in China, Europe, the US, and the UK have reported the use of modifiers made by recycled LDPE independently [
66,
67]. Khan et al. [
68] studied waste LDPE, HDPE, and crumb rubber (CR) as an addition to base bitumen, and showed that modified asphalt binder with 10% LDPE offers the best resistance against rutting compared to HDPE and CR. Ho et al. [
69] investigated combinations of three types of recycled LDPE as asphalt modifiers. The results have shown that the molecular weight and molecular weight distribution of waste LDPE have significant effects on the asphalt’s low-temperature performance, thermal storage stability, and polymer phase distribution. The recycled LDPE with lower molecular weight and wider molecular weight distribution is more suitable for asphalt modification, compared with high molecular weight LDPE with very narrow molecular weight distribution.
- (2)
-
Waste HDPE
如上所述,HDPE的高结晶度使其难以浸入沥青中,这也影响了改性沥青的相容性。人们一致认为,废HDPE改性沥青具有更高的刚度和粘度,以及更好的防潮性
[70]。Costa等人[
37]表明,与SBS改性沥青相比,废弃HDPE改性沥青具有更高的刚度和更低的穿透力,但更差的回弹性和蠕变回收率。
- (3)
-
废旧聚丙烯
再生PP改性沥青具有热塑性聚酯改性沥青的共同特点,特别是高温性能的优越性。然而,废PP的添加降低了改性沥青的延展性,降低了疲劳开裂性能
[71]。具体而言,当5%的废PP被添加到沥青中时,延展性的降低约为20%[71,72]。因此,建议废PP改性沥青适用于高温高湿地区,但粘度需要提高
[45]。
- (4)
-
废聚氯乙烯
最近的研究表明,添加废PVC会增加基础沥青的粘度和刚度,使改性沥青具有更好的抗车辙性。一个可能的原因是PVC中的氯化物和碳键偶极子提供了更大的刚度
[73]。Ziari [
74]的一项研究表明,废聚氯乙烯提高了抗疲劳性,但抗热开裂性较差。值得注意的是,当PVC加热到高温时,氯化氢(HCL)可以形成并排放到大气中[
26]。因此,应采取措施避免空气污染。
- (5)
-
废旧聚酯
根据健康恢复行动计划(WRAP),PET是回收率最高的塑料废物之一[
47]。由于熔点高,大多数研究人员倾向于使用废PET进行干改性
[75]。结果表明,当PET的用量分别为30%和50%时,使用干法开发的废PET改性混合物具有改进的高温性能和降低的抗断裂性
[76]。
- (6)
-
废物 PS
使用干法开发的废PS改性沥青混合物被发现具有更高的刚性,但就抗开裂性而言,这可能是较冷地区的一个问题
[33]。具体而言,与使用干法的废PE,PP和橡胶沥青混合物相比,废PS在改性沥青混合物中表现出最低的弹性行为
[42]。Fang等人
[77]成功地利用了极低密度的PS废料来扩大沥青的刚度并提高其抗车辙性。Hasan等人
[71]表明,在沥青中添加废物高冲击PS(HIPS)可以提高沥青的刚度,但会降低低温性能。此外,应该更加注意当PS加热到70°C以上时会释放有害物质的事实。
- (7)
-
废旧伊娃
废旧EVA与沥青具有良好的相容性,因此已被广泛研究和应用。结果表明,当EVA与沥青混合时,大体积的醋酸乙烯酯基团成为非结晶区域或无定形区域,其起着类似于橡胶的作用。EVA的结晶区具有较高的刚度,起到增强棒的作用,大大提高了改性沥青
[78]的高温稳定性、耐低温开裂性和粘度。当添加少量废物EVA(2-4%)时,它在低温性能方面也表现出一定的改善
[79]。
- (8)
-
废旧 ABS
来自最近研究的证据表明,使用电子塑料粉末进行沥青改性有助于提高沥青的粘度以及混合和混合温度,同时与原始沥青相比降低了车辙敏感性
[80]。ABS改性沥青的低温性能相当于原始沥青粘结剂
[81]。与废旧EVA和PE改性沥青相比,废ABS作为沥青改性剂的性能较差,但似乎具有更好的储存稳定性
[26]。而且,废ABS改性沥青的路面性能优于未改性沥青
[82]。根据机械经验路面设计指南(M-E PDG)[
83],使用干法使用电子废物作为沥青混合物的改性剂将减少沥青层的设计厚度[
84]。
- (9)
-
废聚氨酯
Bazmara et al. [
85] used thermoplastic PU and synthetic PU as modifier additives in asphalt production. The results showed that the addition of synthetic PU increased the asphalt’s viscosity and stiffness. Both types of PU improved the performance of base asphalt at high temperatures, including high rutting resistance and performance grade; however, they had no notable effects on asphalt performance at low temperatures. A similar result was reported by Cong [
86], who noted that waste PU-modified asphalt had good deformation resistance, aging resistance, fatigue resistance, and high-temperature storage performance. Waste PU-modified asphalt mixture developed using the wet method also had excellent water stability and deformation resistance [
87]. Hot-mix asphalts with PU-modified bitumen yielded improvements in stability and lower deformation [
88]. With regard to the PU-modified mixture, Salas et al. showed that, compared with the virgin sample, the PU-modified MA from the wet method exhibited lower indentation, and thus the modified mastic asphalts (MA) can be used for heavy-traffic roads [
89].
Table 2 presents a summary of the effects of waste plastics on asphalt performance with respect to compatibility, high- and low-temperature performance, and viscosity, based on the most recent literature reviewed in this paper. It is evident that the addition of waste plastics can most likely increase the high-temperature stability and viscosity as well as decrease the low-temperature flexibility. Waste LDPE, PP, EVA, ABS, and PU have good compatibility with asphalt compared with other types of waste plastics, which can be seen from the summary of the rheological results of various waste plastic-modified asphalt in Figure 2. The high-temperature rheological property of PP-modified asphalt was the best, followed by PE- and PVC-modified asphalt, and PS-modified asphalt was the least effective. However, further research is needed due to the difference in dosage and asphalt.
Figure 2. Rheological results of various waste plastic-modified asphalts [
36,
91,
92,
93,
94].
Table 2. Characteristics of common waste plastics.
Type |
Characteristics of Waste Plastic |
Reference |
Compatibility |
High-Temperature Stability |
Low-Temperature Flexibility |
Viscosity |
LDPE |
√ |
√ |
- |
√ |
[30] |
HDPE |
|
√ |
- |
|
[31,32] |
PP |
√ |
√ |
- |
√ |
[34,45,90] |
PVC |
- |
√ |
- |
√ |
[35,36] |
PET |
- |
√ |
- |
√ |
[28] |
PS |
- |
√ |
- |
√ |
[33] |
EVA |
√ |
√ |
√ |
√ |
[32,37,38,78] |
ABS |
√ |
√ |
- |
- |
[26] |
PU |
√ |
- |
- |
√ |
[85,87] |
1.3.2. Composite Modification
The application of waste plastic as an independent modifier in asphalt is rare in current studies and engineering practices. This is because the key properties of asphalt cannot be improved by using only one type of waste plastic. In order to enhance and optimize the properties of waste plastic-modified asphalt binder to meet the needs of increased traffic demands, there has been growing interest in composite modification. Recently, more and more studies have investigated the properties of modified asphalt binders containing waste plastic and various materials [
95]. This interesting trend means that the application of waste plastic as an asphalt modifier has been accepted by researchers and engineering practice. Some researchers investigated modified blends containing two or more types of waste plastic. For instance, Brovelli et al. [
96] and García-Morales et al. [
97] assessed the high-temperature stability of base asphalt modified by combining LDPE and EVA. Lai et al. [
98] studied the compatibility and performance of waste HDPE/LDPE/PP-modified asphalt. Other researchers focused on the application of various modified blends of waste plastics and common polymers. Nasr and Pakshir [
99] tested three melt-compounding combinations of waste PET and crumb rubber to improve the rutting and fatigue damage resistance of two base asphalt binders. A study reported by Al-Abdul Wahhab et al. [
44] suggested that waste LDPE/HDPE-modified asphalt, in combination with an elastomeric SBS, can obtain higher recovery and strain resistance, which are better than using the same amount of SBS alone. Additionally, Krzysztof et al. [
100] improved the conventional and thermal properties of asphalt by blending waste LDPE, ground tire rubber (GTR), and elastomer. Other studies have reported that waste plastics can be mixed with some common materials such as sulfur [
101,
102], carbon black [
103], and polyphosphoric acid [
104,
105] as asphalt modifiers.