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Ceramic Membranes: History
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Contributor: Jack Zhong

Ceramic membranes are porous inorganic separation layers in which a metal oxide, carbide or nitride forms the selective barrier [1]. The support is a coarse asymmetric body of compatible ceramic, and successive coating and firing steps deposit layers of decreasing pore size, so the structure is graded from a macroporous support to a microporous skin [1]. Alumina, zirconia, titania and their mixtures set the chemical and thermal envelope, because the oxide decides resistance to acid, to alkali and to temperatures above those that polymer membranes tolerate [2]. Pore size and its distribution, not a dense lattice, separate the ultrafiltration and microfiltration grades from dense ceramic electrolytes [3]. The oxide surface carries hydroxyl groups and a pH-dependent charge, so ionic retention also depends on the electrolyte [1].

  • ceramic membrane
  • asymmetric support
  • inorganic membrane
  • pore size grading
  • alumina

References

  1. Komolikov, Y.I.; Blaginina, L.A.; Technology of Ceramic Micro and Ultrafiltration Membranes (Review). Refractories and Industrial Ceramics 2002, 43, 181-187, 10.1023/a:1020523301886.
  2. Garmash, E.P.; Kryuchkov, Y.N.; Pavlikov, V.N.; Ceramic membranes for ultra- and microfiltration (review). Glass and Ceramics 1995, 52, 150-152, 10.1007/bf00679945.
  3. Li, C.; Sun, W.; Lu, Z.; Ao, X.; Li, S.; Ceramic nanocomposite membranes and membrane fouling: A review. Water Research 2020, 175, 115674, 10.1016/j.watres.2020.115674.
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