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Lithium Batteries: History
Please note this is an old version of this entry, which may differ significantly from the current revision.
Contributor: Jack Zhong

Lithium batteries are rechargeable cells in which lithium ions move between a host negative electrode and a lithium-transition-metal oxide or phosphate positive electrode through a non-aqueous electrolyte, the charge being balanced by electrons in the external circuit. The term covers several chemistries; the lithium-ion version, in which lithium stays in an inserted form at both electrodes, is the one that dominates, and its position rests on a combination of high cell voltage, energy density and long cycle life rather than on any single property [1]. Capacity loss over time is not caused by one mechanism but by several acting together: growth of the surface film on the negative electrode, loss of cyclable lithium, mechanical damage to the electrode coating and, at the positive electrode, transition-metal dissolution and structural change [2]. Electrode materials are chosen against that background, lithium titanate being a case where a higher operating potential is accepted in exchange for almost no volume change and a very long life [3]. Silicon offers roughly ten times the capacity of graphite but expands on lithiation, so it is taken in nanostructured form [4]. Mixed transition-metal oxides store charge by conversion and have been examined in fibrous morphologies [5]. Safety under abuse and the cost of the electrolyte remain the outstanding concerns.

  • lithium-ion battery
  • insertion electrode
  • solid electrolyte interphase
  • graphite anode
  • energy density
  • capacity fade

Advanced Battery Materials and Technologies·Electrical and Electronic Engineering·Engineering·Physical Sciences

 

References

  1. Liu, R.Y.; Recent Progress of Anode and Cathode Materials for Lithium Ion Battery. Materials Science Forum 2021, 1027, 69-75, 10.4028/www.scientific.net/msf.1027.69.
  2. Agubra, V.; Fergus, J.; Lithium Ion Battery Anode Aging Mechanisms. Materials 2013, 6, 1310-1325, 10.3390/ma6041310.
  3. Yi, T.; Bing, X.; Research Progress on Lithium Titanate as Anode Material in Lithium-ion Battery. Journal of Inorganic Materials 2018, 33, 475, 10.15541/jim20170330.
  4. LI, J.W.; ZHOU, A.J.; LIU, X.Q.; LI, J.Z.; Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery. Journal of Inorganic Materials 2013, 28, 1207-1212, 10.3724/sp.j.1077.2013.13125.
  5. Cheng, C.; Hierarchical MnCo2O4 micro/nano fibres as a high-performance anode of lithium-ion battery. Materials Letters 2022, 324, 132770, 10.1016/j.matlet.2022.132770.
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