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Catalytic Partial Oxidation: History
Please note this is an old version of this entry, which may differ significantly from the current revision.
Subjects: Chemistry, Organic
Contributor: Helena Kang

Catalytic partial oxidation is a catalyzed oxidation that converts a substrate into an oxygenated or reformed product of intermediate oxidation state, stopping short of complete conversion to CO2 and H2O [1][2]. In catalysis and oxidation reactions the concept is bounded by that intermediate-oxidation-state product—commonly syngas (CO + H2) from an alcohol or methane, or a partially oxygenated organic molecule—and by a catalyst that directs oxygen insertion or reforming toward that product. Essential features are a limited supply or controlled activation of oxygen, a metal or oxide surface that activates both the substrate and O2 (or lattice oxygen), and a kinetic window in which the desired partial-oxidation product desorbs before further oxidation [2][3]. Alcohols such as methanol and ethanol undergo catalytic partial oxidation to hydrogen-rich mixtures at metal surfaces [1]. Methane partial oxidation over palladium or ruthenium illustrates the same definition at a C1 hydrocarbon: the oxidation state of carbon rises from −4 only as far as the syngas level, and the metal’s oxidation state modulates the product distribution [2][4]. Non-lattice surface oxygen can be the reactive oxidant in hydrocarbon partial oxidation to oxygenated aromatics [3]. The concept is distinguished from total oxidation (combustion) by the incomplete oxidation level of the carbon-containing product, and from steam reforming by the use of oxygen rather than water as the co-reactant.

  • partial oxidation
  • syngas
  • selective oxidation
  • lattice oxygen

Catalysis and Oxidation Reactions • Catalysis • Chemical Engineering • Physical Sciences

References

  1. Keith L. Hohn; Yu‐Chuan Lin; Catalytic Partial Oxidation of Methanol and Ethanol for Hydrogen Generation. ChemSusChem 2009, 2, 927-940, 10.1002/cssc.200900104.
  2. Bertram Kimmerle; Alfons Baiker; Jan-Dierk Grunwaldt; Oscillatory behaviour of catalytic properties, structure and temperature during the catalytic partial oxidation of methane on Pd/Al2O3. Phys. Chem. Chem. Phys. 2010, 12, 2288-2291, 10.1039/b924001b.
  3. Sivaram Pradhan; Jonathan K. Bartley; Donald Bethell; Albert F. Carley; Marco Conte; Stan Golunski; Matthew P. House; Robert L. Jenkins; Rhys Lloyd; Graham J. Hutchings; et al. Non-lattice surface oxygen species implicated in the catalytic partial oxidation of decane to oxygenated aromatics. Nat. Chem. 2012, 4, 134-139, 10.1038/nchem.1245.
  4. Stefan Rabe; Maarten Nachtegaal; Frédéric Vogel; Catalytic partial oxidation of methane to synthesis gas over a ruthenium catalyst: the role of the oxidation state. Phys. Chem. Chem. Phys. 2007, 9, 1461-1468, 10.1039/b617529e.
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