MOFs for Mercury Detection: Comparison
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The advantages of metal organic frameworks (MOFs) are: existence of porosity to adsorb specific analyte, improved aqueous solubility, exceptional photophysical and chemical properties. MOFs are noted as exceptional candidates towards the detection and removal of specific analytes, particular for the detection/removal of environmental contaminants, such as heavy metal ions, toxic anions, hazardous gases, explosives, etc. Among heavy metal ions, mercury has been noted as a global hazard because of its high toxicity in the elemental (Hg0), divalent cationic (Hg2+), and methyl mercury (CH3Hg+) forms. To secure the environment and living organisms, many countries have imposed stringent regulations to monitor mercury at all costs. Regarding the detection/removal requirements of mercury, researchers have proposed and reported all kinds of MOFs-based luminescent/non-luminescent probes towards mercury.This review provides valuable information about the MOFs which have been engaged in detection and removal of elemental mercury and Hg2+ ions. Moreover, the involved mechanisms or adsorption isotherms related to sensors or removal studies are clarified for the readers. Finally, advantages and limitations of MOFs in mercury detection/removal are described together with future scopes.

  • Hg2+
  • CH3Hg+
  • elemental mercury
  • MOFs
  • luminescent detection
  • adsorption isotherms
  • real analysis
  • non-luminescent probes
  • organic linkers
  • metal nodes
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References

  1. Huang, J.-H.; Shetaya, W.H.; Osterwalder, S. Determination of (Bio)-available mercury in soils: A review. Environ. Pollut. 2020, 263, 114323.Yee, K.-K.; Reimer, N.; Liu, J.; Cheng, S.-Y.; Yiu, S.-M.; Weber, J.; Stock, N.; Xu, Z. Effective Mercury Sorption by Thiol-Laced Metal–Organic Frameworks: In Strong Acid and the Vapor Phase. J. Am. Chem. Soc. 2013, 135, 7795–7798.
  2. Botasini, S.; Heijo, G.; Méndez, E. Toward decentralized analysis of mercury (II) in real samples. A critical review on nanotechnology-based methodologies. Anal. Chim. Acta 2013, 800, 1–11.Wang, Q.; Astruc, D. State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanoca-talysis. Chem. Rev. 2020, 120, 1438–1511.
  3. Xie, Z.-J.; Bao, X.-Y.; Peng, C.-F. Highly Sensitive and Selective Colorimetric Detection of Methylmercury Based on DNA Functionalized Gold Nanoparticles. Sensors 2018, 18, 2679.Kumar, P.; Deep, A.; Kim, K.-H. Metal organic frameworks for sensing applications. TrAC Trends Anal. Chem. 2015, 73, 39–53.
  4. Shellaiah, M.; Simon, T.; Venkatesan, P.; Sun, K.W.; Ko, F.-H.; Wu, S.-P. Cysteamine-modified diamond nanoparticles applied in cellular imaging and Hg2+ ions detection. Appl. Surf. Sci. 2019, 465, 340–350.Lee, K.J.; Lee, J.H.; Jeoung, S.; Moon, H.R. Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights. Acc. Chem. Res. 2017, 50, 2684–2692.
  5. Aderinto, S.O. Fluorescent, colourimetric, and ratiometric probes based on diverse fluorophore motifs for mercuric(II) ion (Hg2+) sensing: Highlights from 2011 to 2019. Chem. Pap. 2020, 74, 3195–3232.Cui, J.; Ren, S.; Sun, B.; Jia, S. Optimization protocols and improved strategies for metal-organic frameworks for immobilizing enzymes: Current development and future challenges. Coord. Chem. Rev. 2018, 370, 22–41.
  6. Kobielska, P.A.; Howarth, A.J.; Farha, O.K.; Nayak, S. Metal–organic frameworks for heavy metal removal from water. Coord. Chem. Rev. 2018, 358, 92–107.Hu, M.-L.; Razavi, S.A.A.; Piroozzadeh, M.; Morsali, A. Sensing organic analytes by metal–organic frameworks: A new way of considering the topic. Inorg. Chem. Front. 2020, 7, 1598–1632.
  7. Selid, P.D.; Xu, H.; Collins, E.M.; Face-Collins, M.S.; Zhao, J.X. Sensing Mercury for Biomedical and Environmental Monitoring. Sensors 2009, 9, 5446–5459.Dalapati, R.; Biswas, S. Post-synthetic modification of a metal-organic framework with fluorescent-tag for dual naked-eye sensing in aqueous medium. Sens. Actuators B Chem. 2017, 239, 759–767.
  8. Bernhoft, R.A. Mercury Toxicity and Treatment: A Review of the Literature. J. Environ. Public Health 2011, 2012, 1–10.Shellaiah, M.; Sun, K.W. Review on Sensing Applications of Perovskite Nanomaterials. Chemosensors 2020, 8, 55.
  9. Langford, N.J.; Ferner, R.E. Toxicity of mercury. J. Hum. Hypertens. 1999, 13, 651–656.Yang, J.; Wang, Z.; Li, Y.; Zhuang, Q.; Zhao, W.; Gu, J. Porphyrinic MOFs for reversible fluorescent and colorimetric sensing of mercury(II) ions in aqueous phase. RSC Adv. 2016, 6, 69807–69814.
  10. Rana, M.; Balcioglu, M.; Robertson, N.M.; Hizir, M.S.; Yumak, S.; Yigit, M.V. Low picomolar, instrument-free visual detection of mercury and silver ions using low-cost programmable nanoprobes. Chem. Sci. 2017, 8, 1200–1208.Zhang, X.; Xia, T.; Jiang, K.; Cui, Y.; Yang, Y.; Qian, G. Highly sensitive and selective detection of mercury (II) based on a zirconium metal-organic framework in aqueous media. J. Solid State Chem. 2017, 253, 277–281.
  11. Gauthama, B.; Narayana, B.; Sarojini, B.; Suresh, N.; Sangappa, Y.; Kudva, A.K.; Satyanarayana, G.; Raghu, S.V. Colorimetric “off–on” fluorescent probe for selective detection of toxic Hg2+ based on rhodamine and its application for in-vivo bioimaging. Microchem. J. 2021, 166, 106233.Samanta, P.; Desai, A.V.; Sharma, S.; Chandra, P.; Ghosh, S.K. Selective Recognition of Hg2+ ion in Water by a Functionalized Metal–Organic Framework (MOF) Based Chemodosimeter. Inorg. Chem. 2018, 57, 2360–2364.
  12. Busairi, N.; Syahir, A. Recent Advances in Mercury Detection: Towards Enabling a Sensitive and Rapid Point-of-Check Measurement. J. Toxicol. Risk Assess 2018, 4, 010.Xiaoxiong, Z.; Wenjun, Z.; Cuiliu, L.; Xiaohong, Q.; Chengyu, Z. Eu3+-Postdoped UIO-66-Type Metal-Organic Framework as a Luminescent Sensor for Hg2+ Detection in Aqueous Media. Inorg. Chem. 2019, 58, 3910–3915.
  13. Nolan, E.M.; Lippard, S.J. Tools and Tactics for the Optical Detection of Mercuric Ion. Chem. Rev. 2008, 108, 3443–3480.Wang, Z.; Yang, J.; Li, Y.; Zhuang, Q.; Gu, J. Zr-Based MOFs integrated with a chromophoric ruthenium complex for specific and reversible Hg2+sensing. Dalton Trans. 2018, 47, 5570–5574.
  14. Shellaiah, M.; Sun, K.W. Luminescent Metal Nanoclusters for Potential Chemosensor Applications. Chemosensors 2017, 5, 36.Li, W.-Y.; Yang, S.; Li, Y.-A.; Li, Q.-Y.; Guan, Q.; Dong, Y.-B. Synthesis of an MOF-based Hg2+-fluorescent probe via stepwise post-synthetic modification in a single-crystal-to-single-crystal fashion and its application in bioimaging. Dalton Trans. 2019, 48, 16502–16508.
  15. Shuai, H.; Xiang, C.; Qian, L.; Bin, F.; Xiaohui, L.; Jipeng, D.; Chang, Z.; Jiahui, L.; Wenbin, Z. Fluorescent sensors for detection of mercury: From small molecules to nanoprobes. Dyes Pigment. 2021, 187, 109125.Kim, J.; Oh, J.S.; Park, K.C.; Gupta, G.; Lee, C.Y. Colorimetric detection of heavy metal ions in water via metal-organic framework. Inorg. Chim. Acta 2019, 486, 69–73.
  16. Dai, D.; Li, Z.; Yang, J.; Wang, C.; Wu, J.-R.; Wang, Y.; Zhang, D.; Yang, Y.-W. Supramolecular Assembly-Induced Emission Enhancement for Efficient Mercury(II) Detection and Removal. J. Am. Chem. Soc. 2019, 141, 4756–4763.Wang, H.; Wang, X.; Liang, M.; Chen, G.; Kong, R.-M.; Xia, L.; Qu, F. A Boric Acid-Functionalized Lanthanide Metal-Organic Framework as a Fluorescence “Turn-on” Probe for Selective Monitoring of Hg2+ and CH3Hg+. Anal. Chem. 2020, 92, 3366–3372.
  17. Zhao, L.; Zhang, Z.; Liu, Y.; Wei, J.; Liu, Q.; Ran, P.; Li, X. Fibrous strips decorated with cleavable aggregation-induced emission probes for visual detection of Hg2+. J. Hazard. Mater. 2020, 385, 121556.Xia, T.; Song, T.; Zhang, G.; Cui, Y.; Yang, Y.; Wang, Z.; Qian, G. A Terbium Metal-Organic Framework for Highly Selective and Sensitive Luminescence Sensing of Hg2+ Ions in Aqueous Solution. Chem. A Eur. J. 2016, 22, 18429–18434.
  18. Kumar, P.; Deep, A.; Kim, K.-H. Metal organic frameworks for sensing applications. TrAC Trends Anal. Chem. 2015, 73, 39–53.Liu, X.; Lin, H.; Xiao, Z.; Fan, W.; Huang, A.; Wang, R.; Zhang, L.; Sun, D. Multifunctional lanthanide–organic frameworks for fluorescent sensing, gas separation and catalysis. Dalton Trans. 2016, 45, 3743–3749.
  19. Li, Y.; Hu, T.; Chen, R.; Xiang, R.; Wang, Q.; Zeng, Y.; He, C. Novel thiol-functionalized covalent organic framework as adsorbent for simultaneous removal of BTEX and mercury (II) from water. Chem. Eng. J. 2020, 398, 125566.Razavi, S.A.A.; Masoomi, M.Y.; Morsali, A. Double Solvent Sensing Method for Improving Sensitivity and Accuracy of Hg(II) Detection Based on Different Signal Transduction of a Tetrazine-Functionalized Pillared Metal-Organic Framework. Inorg. Chem. 2017, 56, 9646–9652.
  20. Chen, L.; Liu, D.; Peng, J.; Du, Q.; He, H. Ratiometric fluorescence sensing of metal-organic frameworks: Tactics and perspectives. Coord. Chem. Rev. 2020, 404, 213113.Wan, Y.; Zou, D.; Cui, Y.; Yang, Y.; Qian, G. A Zn based anionic metal-organic framework for trace Hg2+ ion detection. J. Solid State Chem. 2018, 266, 70–73.
  21. Razavi, S.A.A.; Morsali, A. Metal ion detection using luminescent-MOFs: Principles, strategies and roadmap. Coord. Chem. Rev. 2020, 415, 213299.Pankajakshan, A.; Kuznetsov, D.; Mandal, S. Ultrasensitive Detection of Hg(II) Ions in Aqueous Medium Using Zinc-Based Metal-Organic Framework. Inorg. Chem. 2019, 58, 1377–1381.
  22. Devaraj, M.; Sasikumar, Y.; Rajendran, S.; Ponce, L.C. Review—Metal Organic Framework Based Nanomaterials for Electrochemical Sensing of Toxic Heavy Metal Ions: Progress and Their Prospects. J. Electrochem. Soc. 2021, 168, 037513.Khatun, A.; Panda, D.K.; Sayresmith, N.; Walter, M.G.; Saha, S. Thiazolothiazole-Based Luminescent Metal-Organic Frameworks with Ligand-to-Ligand Energy Transfer and Hg2+-Sensing Capabilities. Inorg. Chem. 2019, 58, 12707–12715.
  23. Vardali, S.C.; Manousi, N.; Barczak, M.; Giannakoudakis, D.A. Novel Approaches Utilizing Metal-Organic Framework Composites for the Extraction of Organic Compounds and Metal Traces from Fish and Seafood. Molecules 2020, 25, 513.Jiang, J.; Lu, Y.; Liu, J.; Zhou, Y.; Zhao, D.; Li, C. An acid-base resistant Zn-based metal-organic framework as a luminescent sensor for mercury(II). J. Solid State Chem. 2020, 283, 121153.
  24. Li, X.; Ma, W.; Li, H.; Zhang, Q.; Liu, H. Sulfur-functionalized metal-organic frameworks: Synthesis and applications as advanced adsorbents. Coord. Chem. Rev. 2020, 408, 213191.Wu, P.; Liu, Y.; Liu, Y.; Wang, J.; Li, Y.; Liu, W.; Wang, J. Cadmium-Based Metal-Organic Framework as a Highly Selective and Sensitive Ratiometric Luminescent Sensor for Mercury(II). Inorg. Chem. 2015, 54, 11046–11048.
  25. Chen, L.; Luque, R.; Li, Y. Controllable design of tunable nanostructures inside metal–organic frameworks. Chem. Soc. Rev. 2017, 46, 4614–4630.Liu, B.-H.; Liu, D.-X.; Yang, K.-Q.; Dong, S.-J.; Li, W.; Wang, Y.-J. A new cluster-based metal-organic framework with triazine backbones for selective luminescent detection of mercury(II) ion. Inorg. Chem. Commun. 2018, 90, 61–64.
  26. Xia, W.; Mahmood, A.; Zou, R.; Xu, Q. Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion. Energy Environ. Sci. 2015, 8, 1837–1866.El Taher, B.J.; Sabouni, R.; Ghommem, M. Luminescent metal organic framework for selective detection of mercury in aqueous media: Microwave-based synthesis and evaluation. Colloids Surf. A Physicochem. Eng. Asp. 2020, 607, 125477.
  27. Lee, K.J.; Lee, J.H.; Jeoung, S.; Moon, H.R. Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights. Acc. Chem. Res. 2017, 50, 2684–2692.Basaleh, A.S.; Sheta, S.M. Novel advanced nanomaterial based on ferrous metal-organic framework and its application as chemosensors for mercury in environmental and biological samples. Anal. Bioanal. Chem. 2020, 412, 3153–3165.
  28. Xie, Z.; Xu, W.; Cui, X.; Wang, Y. Recent Progress in Metal–Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications. ChemSusChem 2017, 10, 1645–1663.Li, Y.; Ma, D.; Chen, C.; Chen, M.; Li, Z.; Wu, Y.; Zhu, S.; Peng, G. A hydrostable and bromine-functionalized manganese-organic framework with luminescence sensing of Hg2+ and antiferromagnetic properties. J. Solid State Chem. 2019, 269, 257–263.
  29. Song, Y.; Li, X.; Sun, L.; Wang, L. Metal/metal oxide nanostructures derived from metal–organic frameworks. RSC Adv. 2014, 5, 7267–7279.Song, Y.; Fan, R.; Fan, J.; Xing, K.; Du, X.; Wang, P.; Yang, Y. Highly sensitive and selective fluorescent probes for Hg2+ in Ag(i)/Cu(ii) 3D supramolecular architectures based on noncovalent interactions. Dalton Trans. 2016, 45, 16422–16432.
  30. Heo, D.Y.; Do, H.H.; Ahn, S.H.; Kim, S.Y. Metal-Organic Framework Materials for Perovskite Solar Cells. Polymers 2020, 12, 2061.Jana, A.K.; Natarajan, S. Fluorescent Metal-Organic Frameworks for Selective Sensing of Toxic Cations (Tl3+, Hg2+) and Highly Oxidizing Anions ((CrO4)2−, (Cr2O7)2−, (MnO4)−). ChemPlusChem 2017, 82, 1153–1163.
  31. Kaur, H.; Sundriyal, S.; Pachauri, V.; Ingebrandt, S.; Kim, K.-H.; Sharma, A.L.; Deep, A. Luminescent metal-organic frameworks and their composites: Potential future materials for organic light emitting displays. Coord. Chem. Rev. 2019, 401, 213077.Xiao, J.; Liu, J.; Gao, X.; Ji, G.; Wang, D.; Liu, Z. A multi-chemosensor based on Zn-MOF: Ratio-dependent color transition detection of Hg (II) and highly sensitive sensor of Cr (VI). Sens. Actuators B Chem. 2018, 269, 164–172.
  32. Wu, G.; Huang, J.; Zang, Y.; He, J.; Xu, G. Porous Field-Effect Transistors Based on a Semiconductive Metal–Organic Framework. J. Am. Chem. Soc. 2017, 139, 1360–1363.Fu, H.-R.; Zhao, Y.; Xie, T.; Han, M.-L.; Ma, L.-F.; Zang, S.-Q. Stable dye-encapsulated indium-organic framework as dual-emitting sensor for the detection of Hg2+/Cr2O72− and a wide range of nitro-compounds. J. Mater. Chem. C 2018, 6, 6440–6448.
  33. He, J.; Xu, J.; Yin, J.; Li, N.; Bu, X.-H. Recent advances in luminescent metal-organic frameworks for chemical sensors. Sci. China Mater. 2019, 62, 1655–1678.Li, F.; Hong, Y.-S.; Zuo, K.-X.; Sun, Q.; Gao, E.-Q. Highly selective fluorescent probe for Hg2+ and MnO4− by the two-fold interpenetrating metal-organic framework with nitro functionalized linkers. J. Solid State Chem. 2019, 270, 509–515.
  34. Wu, S.; Min, H.; Shi, W.; Cheng, P. Multicenter Metal–Organic Framework-Based Ratiometric Fluorescent Sensors. Adv. Mater. 2020, 32, 1805871.Yang, Y.-J.; Liu, D.; Li, Y.-H.; Dong, G.-Y. Two new luminescent ternary Cd(II)-MOFs by regulation of aromatic dicarboxylate ligands used as efficient dual-responsive sensors for toxic metal ions in water. Polyhedron 2019, 159, 32–42.
  35. Samanta, P.; Let, S.; Mandal, W.; Dutta, S.; Ghosh, S.K. Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants. Inorg. Chem. Front. 2020, 7, 1801–1821.Mahmoud, M.E.; Moussa, Z.; Prakasam, T.; Li, L.; Abiad, M.G.; Patra, D.; Hmadeh, M. Lanthanides based metal organic frameworks for luminescence sensing of toxic metal ions. J. Solid State Chem. 2020, 281, 121031.
  36. Huang, S.-Z.; Liu, S.-S.; Zhang, H.-j.; Han, Z.; Zhao, G.; Dong, X.-Y.; Zang, S.-Q. Dual-Functional Proton-Conducting and pH-Sensing Polymer Membrane Benefiting from a Eu-MOF. ACS Appl. Mater. Interfaces 2020, 12, 28720–28726.Ren, M.; Wang, H.; Liu, Y.; Ma, Q.; Jia, W.; Liu, M.; Wang, H.; Lu, Y. Fluorescent Determination of Mercury (II) and Glutathione Using Amino-MIL-53(Al) Nanosheets. Anal. Lett. 2020, 53, 2700–2714.
  37. Wang, Y.; Hu, Y.; He, Q.; Yan, J.; Xiong, H.; Wen, N.; Cai, S.; Peng, D.; Liu, Y.; Liu, Z. Metal-organic frameworks for virus detection. Biosens. Bioelectron. 2020, 169, 112604.Yang, L.; Li, X.; Qin, C.; Shao, K.-Z.; Su, Z.-M. A fluorescent sensor for highly selective sensing of nitro explosives and Hg(ii) ions based on a 3D porous layer metal–organic framework. CrystEngComm 2016, 18, 4765–4771.
  38. Gai, S.; Zhang, J.; Fan, R.; Xing, K.; Chen, W.; Zhu, K.; Zheng, X.; Wang, P.; Fang, X.; Yang, Y. Highly Stable Zinc-Based Metal-Organic Frameworks and Corresponding Flexible Composites for Removal and Detection of Antibiotics in Water. ACS Appl. Mater. Interfaces 2020, 12, 8650–8662.Gong, W.-J.; Ren, Z.-G.; Li, H.-X.; Zhang, J.-G.; Lang, J.-P. Cadmium(II) Coordination Polymers of 4-Pyr-poly-2-ene and Carboxylates: Construction, Structure, and Photochemical Double [2 + 2] Cycloaddition and Luminescent Sensing of Nitroaromatics and Mercury(II) Ions. Cryst. Growth Des. 2017, 17, 870–881.
  39. Tang, J.; Feng, D.; Yang, J.; Ma, X.; Wang, X.-Q. A turn-on luminescent probe for Fe3+ and ascorbic acid with logic gate operation based on a zinc(ii)-based metal–organic framework. New J. Chem. 2020, 44, 8728–8735.Su, Y.-Q.; Qu, Y.-H.; Fu, L.; Cui, G.-H. An unprecedented binodal (4,6)-connected Co(II) MOF as dual-responsive luminescent sensor for detection of acetylacetone and Hg2+ ions. Inorg. Chem. Commun. 2020, 118, 108013.
  40. Wu, R.-Z.; Yang, X.; Zhang, L.-W.; Zhou, P.-P. Luminescent lanthanide metal–organic frameworks for chemical sensing and toxic anion detection. Dalton Trans. 2017, 46, 9859–9867.
  41. Hu, Z.; Deibert, B.J.; Li, J. Luminescent metal–organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815–5840.
  42. Dalapati, R.; Nandi, S.; Biswas, S. Post-synthetic modification of a metal-organic framework with a chemodosimeter for the rapid detection of lethal cyanide via dual emission. Dalton Trans. 2020, 49, 8684–8692.
  43. Koo, W.-T.; Jang, J.-S.; Kim, I.-D. Metal-Organic Frameworks for Chemiresistive Sensors. Chem 2019, 5, 1938–1963.
  44. Lustig, W.P.; Mukherjee, S.; Rudd, N.D.; Desai, A.V.; Li, J.; Ghosh, S.K. Metal–organic frameworks: Functional luminescent and photonic materials for sensing applications. Chem. Soc. Rev. 2017, 46, 3242–3285.
  45. Goswami, R.; Mandal, S.C.; Pathak, B.; Neogi, S. Guest-Induced Ultrasensitive Detection of Multiple Toxic Organics and Fe3+ Ions in a Strategically Designed and Regenerative Smart Fluorescent Metal-Organic Framework. ACS Appl. Mater. Interfaces 2019, 11, 9042–9053.
  46. Tchalala, M.R.; Bhatt, P.M.; Chappanda, K.N.; Tavares, S.R.; Adil, K.; Belmabkhout, Y.; Shkurenko, A.; Cadiau, A.; Heymans, N.; De Weireld, G.; et al. Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air. Nat. Commun. 2019, 10, 1–10.
  47. Chen, G.; Guo, Z.; Zeng, G.; Tang, L. Fluorescent and colorimetric sensors for environmental mercury detection. Analyst 2015, 140, 5400–5443.
  48. Rouhani, F.; Morsali, A. Goal-Directed Design of Metal-Organic Frameworks for HgII and PbII Adsorption from Aqueous Solutions. Chem. Eur. J. 2018, 24, 17170–17179.
  49. Tan, H.; Liu, B.; Chen, Y. Lanthanide Coordination Polymer Nanoparticles for Sensing of Mercury(II) by Photoinduced Electron Transfer. ACS Nano 2012, 6, 10505–10511.
  50. Sohrabi, M.R. Preconcentration of mercury(II) using a thiol-functionalized metal-organic framework nanocomposite as a sorbent. Microchim. Acta 2014, 181, 435–444.
  51. Zhang, X.; Shen, B.; Zhu, S.; Xu, H.; Tian, L. UiO-66 and its Br-modified derivates for elemental mercury removal. J. Hazard. Mater. 2016, 320, 556–563.
  52. Li, X.; Wang, B.; Cao, Y.; Zhao, S.; Wang, H.; Feng, X.; Zhou, J.; Ma, X. Water Contaminant Elimination Based on Metal–Organic Frameworks and Perspective on Their Industrial Applications. ACS Sustain. Chem. Eng. 2019, 7, 4548–4563.
  53. Fang, X.; Zong, B.; Mao, S. Metal-Organic Framework-Based Sensors for Environmental Contaminant Sensing. Nano-Micro Lett. 2018, 10, 1–19.
  54. Yao, C.-X.; Zhao, N.; Liu, J.-C.; Chen, L.-J.; Liu, J.-M.; Fang, G.-Z.; Wang, S. Recent Progress on Luminescent Metal-Organic Framework-Involved Hybrid Materials for Rapid Determination of Contaminants in Environment and Food. Polymers 2020, 12, 691.
  55. Yee, K.-K.; Reimer, N.; Liu, J.; Cheng, S.-Y.; Yiu, S.-M.; Weber, J.; Stock, N.; Xu, Z. Effective Mercury Sorption by Thiol-Laced Metal–Organic Frameworks: In Strong Acid and the Vapor Phase. J. Am. Chem. Soc. 2013, 135, 7795–7798.
  56. Wang, Q.; Astruc, D. State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanoca-talysis. Chem. Rev. 2020, 120, 1438–1511.
  57. Cui, J.; Ren, S.; Sun, B.; Jia, S. Optimization protocols and improved strategies for metal-organic frameworks for immobilizing enzymes: Current development and future challenges. Coord. Chem. Rev. 2018, 370, 22–41.
  58. Hu, M.-L.; Razavi, S.A.A.; Piroozzadeh, M.; Morsali, A. Sensing organic analytes by metal–organic frameworks: A new way of considering the topic. Inorg. Chem. Front. 2020, 7, 1598–1632.
  59. Dalapati, R.; Biswas, S. Post-synthetic modification of a metal-organic framework with fluorescent-tag for dual naked-eye sensing in aqueous medium. Sens. Actuators B Chem. 2017, 239, 759–767.
  60. Safaei, M.; Foroughi, M.M.; Ebrahimpoor, N.; Jahani, S.; Omidi, A.; Khatami, M. A review on metal-organic frameworks: Synthesis and applications. TrAC Trends Anal. Chem. 2019, 118, 401–425.
  61. Al-Ghoul, M.; Issa, R.; Hmadeh, M. Synthesis, size and structural evolution of metal–organic framework-199 via a reaction–diffusion process at room temperature. CrystEngComm 2016, 19, 608–612.
  62. Al Amery, N.; Abid, H.; Al-Saadi, S.; Wang, S.; Liu, S. Facile directions for synthesis, modification and activation of MOFs. Mater. Today Chem. 2020, 17, 100343.
  63. Klinowski, J.; Almeida Paz, F.A.; Silva, P.; Rocha, J. Microwave-Assisted Synthesis of Metal-Organic Frameworks. Dalton Trans. 2011, 40, 321–330.
  64. Thomas-Hillman, I.; Laybourn, A.; Dodds, C.; Kingman, S.W. Realising the environmental benefits of metal-organic frameworks: Recent advances in microwave synthesis. J. Mater. Chem. A 2018, 6, 11564–11581.
  65. Le, V.N.; Kwon, H.T.; Vo, T.K.; Kim, J.-H.; Kim, W.-S.; Kim, J. Microwave-assisted continuous flow synthesis of mesoporous metal-organic framework MIL-100 (Fe) and its application to Cu(I)-loaded adsorbent for CO/CO2 separation. Mater. Chem. Phys. 2020, 253, 123278.
  66. Li, W.-J.; Tu, M.; Cao, R.; Fischer, R.A. Metal-organic framework thin films: Electrochemical fabrication techniques and corresponding applications & perspectives. J. Mater. Chem. A 2016, 4, 12356–12369.
  67. Wang, Z.; Li, Z.; Ng, M.; Milner, P.J. Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base. Dalton Trans. 2020, 49, 16238–16244.
  68. Vaitsis, C.; Sourkouni, G.; Argirusis, C. Chapter 11—Sonochemical synthesis of MOFs. In Metal-Organic Frameworks for Bio-medical Applications; Mozafari, M., Ed.; Woodhead Publishing: Cambridge, UK, 2020; pp. 223–244.
  69. Kalaj, M.; Cohen, S.M. Postsynthetic Modification: An Enabling Technology for the Advancement of Metal-Organic Frameworks. ACS Cent. Sci. 2020, 6, 1046–1057.
  70. Shellaiah, M.; Sun, K.W. Review on Sensing Applications of Perovskite Nanomaterials. Chemosensors 2020, 8, 55.
  71. Yang, J.; Wang, Z.; Li, Y.; Zhuang, Q.; Zhao, W.; Gu, J. Porphyrinic MOFs for reversible fluorescent and colorimetric sensing of mercury(II) ions in aqueous phase. RSC Adv. 2016, 6, 69807–69814.
  72. Zhang, X.; Xia, T.; Jiang, K.; Cui, Y.; Yang, Y.; Qian, G. Highly sensitive and selective detection of mercury (II) based on a zirconium metal-organic framework in aqueous media. J. Solid State Chem. 2017, 253, 277–281.
  73. Samanta, P.; Desai, A.V.; Sharma, S.; Chandra, P.; Ghosh, S.K. Selective Recognition of Hg2+ ion in Water by a Functionalized Metal–Organic Framework (MOF) Based Chemodosimeter. Inorg. Chem. 2018, 57, 2360–2364.
  74. Xiaoxiong, Z.; Wenjun, Z.; Cuiliu, L.; Xiaohong, Q.; Chengyu, Z. Eu3+-Postdoped UIO-66-Type Metal-Organic Framework as a Luminescent Sensor for Hg2+ Detection in Aqueous Media. Inorg. Chem. 2019, 58, 3910–3915.
  75. Wang, Z.; Yang, J.; Li, Y.; Zhuang, Q.; Gu, J. Zr-Based MOFs integrated with a chromophoric ruthenium complex for specific and reversible Hg2+sensing. Dalton Trans. 2018, 47, 5570–5574.
  76. Li, W.-Y.; Yang, S.; Li, Y.-A.; Li, Q.-Y.; Guan, Q.; Dong, Y.-B. Synthesis of an MOF-based Hg2+-fluorescent probe via stepwise post-synthetic modification in a single-crystal-to-single-crystal fashion and its application in bioimaging. Dalton Trans. 2019, 48, 16502–16508.
  77. Kim, J.; Oh, J.S.; Park, K.C.; Gupta, G.; Lee, C.Y. Colorimetric detection of heavy metal ions in water via metal-organic framework. Inorg. Chim. Acta 2019, 486, 69–73.
  78. Wang, H.; Wang, X.; Liang, M.; Chen, G.; Kong, R.-M.; Xia, L.; Qu, F. A Boric Acid-Functionalized Lanthanide Metal-Organic Framework as a Fluorescence “Turn-on” Probe for Selective Monitoring of Hg2+ and CH3Hg+. Anal. Chem. 2020, 92, 3366–3372.
  79. Xia, T.; Song, T.; Zhang, G.; Cui, Y.; Yang, Y.; Wang, Z.; Qian, G. A Terbium Metal-Organic Framework for Highly Selective and Sensitive Luminescence Sensing of Hg2+ Ions in Aqueous Solution. Chem. A Eur. J. 2016, 22, 18429–18434.
  80. Liu, X.; Lin, H.; Xiao, Z.; Fan, W.; Huang, A.; Wang, R.; Zhang, L.; Sun, D. Multifunctional lanthanide–organic frameworks for fluorescent sensing, gas separation and catalysis. Dalton Trans. 2016, 45, 3743–3749.
  81. Razavi, S.A.A.; Masoomi, M.Y.; Morsali, A. Double Solvent Sensing Method for Improving Sensitivity and Accuracy of Hg(II) Detection Based on Different Signal Transduction of a Tetrazine-Functionalized Pillared Metal-Organic Framework. Inorg. Chem. 2017, 56, 9646–9652.
  82. Wan, Y.; Zou, D.; Cui, Y.; Yang, Y.; Qian, G. A Zn based anionic metal-organic framework for trace Hg2+ ion detection. J. Solid State Chem. 2018, 266, 70–73.
  83. Pankajakshan, A.; Kuznetsov, D.; Mandal, S. Ultrasensitive Detection of Hg(II) Ions in Aqueous Medium Using Zinc-Based Metal-Organic Framework. Inorg. Chem. 2019, 58, 1377–1381.
  84. Khatun, A.; Panda, D.K.; Sayresmith, N.; Walter, M.G.; Saha, S. Thiazolothiazole-Based Luminescent Metal-Organic Frameworks with Ligand-to-Ligand Energy Transfer and Hg2+-Sensing Capabilities. Inorg. Chem. 2019, 58, 12707–12715.
  85. Jiang, J.; Lu, Y.; Liu, J.; Zhou, Y.; Zhao, D.; Li, C. An acid-base resistant Zn-based metal-organic framework as a luminescent sensor for mercury(II). J. Solid State Chem. 2020, 283, 121153.
  86. Wu, P.; Liu, Y.; Liu, Y.; Wang, J.; Li, Y.; Liu, W.; Wang, J. Cadmium-Based Metal-Organic Framework as a Highly Selective and Sensitive Ratiometric Luminescent Sensor for Mercury(II). Inorg. Chem. 2015, 54, 11046–11048.
  87. Liu, B.-H.; Liu, D.-X.; Yang, K.-Q.; Dong, S.-J.; Li, W.; Wang, Y.-J. A new cluster-based metal-organic framework with triazine backbones for selective luminescent detection of mercury(II) ion. Inorg. Chem. Commun. 2018, 90, 61–64.
  88. El Taher, B.J.; Sabouni, R.; Ghommem, M. Luminescent metal organic framework for selective detection of mercury in aqueous media: Microwave-based synthesis and evaluation. Colloids Surf. A Physicochem. Eng. Asp. 2020, 607, 125477.
  89. Basaleh, A.S.; Sheta, S.M. Novel advanced nanomaterial based on ferrous metal-organic framework and its application as chemosensors for mercury in environmental and biological samples. Anal. Bioanal. Chem. 2020, 412, 3153–3165.
  90. Li, Y.; Ma, D.; Chen, C.; Chen, M.; Li, Z.; Wu, Y.; Zhu, S.; Peng, G. A hydrostable and bromine-functionalized manganese-organic framework with luminescence sensing of Hg2+ and antiferromagnetic properties. J. Solid State Chem. 2019, 269, 257–263.
  91. Song, Y.; Fan, R.; Fan, J.; Xing, K.; Du, X.; Wang, P.; Yang, Y. Highly sensitive and selective fluorescent probes for Hg2+ in Ag(i)/Cu(ii) 3D supramolecular architectures based on noncovalent interactions. Dalton Trans. 2016, 45, 16422–16432.
  92. Jana, A.K.; Natarajan, S. Fluorescent Metal-Organic Frameworks for Selective Sensing of Toxic Cations (Tl3+, Hg2+) and Highly Oxidizing Anions ((CrO4)2−, (Cr2O7)2−, (MnO4)−). ChemPlusChem 2017, 82, 1153–1163.
  93. Xiao, J.; Liu, J.; Gao, X.; Ji, G.; Wang, D.; Liu, Z. A multi-chemosensor based on Zn-MOF: Ratio-dependent color transition detection of Hg (II) and highly sensitive sensor of Cr (VI). Sens. Actuators B Chem. 2018, 269, 164–172.
  94. Fu, H.-R.; Zhao, Y.; Xie, T.; Han, M.-L.; Ma, L.-F.; Zang, S.-Q. Stable dye-encapsulated indium-organic framework as dual-emitting sensor for the detection of Hg2+/Cr2O72− and a wide range of nitro-compounds. J. Mater. Chem. C 2018, 6, 6440–6448.
  95. Li, F.; Hong, Y.-S.; Zuo, K.-X.; Sun, Q.; Gao, E.-Q. Highly selective fluorescent probe for Hg2+ and MnO4− by the two-fold interpenetrating metal-organic framework with nitro functionalized linkers. J. Solid State Chem. 2019, 270, 509–515.
  96. Yang, Y.-J.; Liu, D.; Li, Y.-H.; Dong, G.-Y. Two new luminescent ternary Cd(II)-MOFs by regulation of aromatic dicarboxylate ligands used as efficient dual-responsive sensors for toxic metal ions in water. Polyhedron 2019, 159, 32–42.
  97. Mahmoud, M.E.; Moussa, Z.; Prakasam, T.; Li, L.; Abiad, M.G.; Patra, D.; Hmadeh, M. Lanthanides based metal organic frameworks for luminescence sensing of toxic metal ions. J. Solid State Chem. 2020, 281, 121031.
  98. Ren, M.; Wang, H.; Liu, Y.; Ma, Q.; Jia, W.; Liu, M.; Wang, H.; Lu, Y. Fluorescent Determination of Mercury (II) and Glutathione Using Amino-MIL-53(Al) Nanosheets. Anal. Lett. 2020, 53, 2700–2714.
  99. Yang, L.; Li, X.; Qin, C.; Shao, K.-Z.; Su, Z.-M. A fluorescent sensor for highly selective sensing of nitro explosives and Hg(ii) ions based on a 3D porous layer metal–organic framework. CrystEngComm 2016, 18, 4765–4771.
  100. Gong, W.-J.; Ren, Z.-G.; Li, H.-X.; Zhang, J.-G.; Lang, J.-P. Cadmium(II) Coordination Polymers of 4-Pyr-poly-2-ene and Carboxylates: Construction, Structure, and Photochemical Double [2 + 2] Cycloaddition and Luminescent Sensing of Nitroaromatics and Mercury(II) Ions. Cryst. Growth Des. 2017, 17, 870–881.
  101. Su, Y.-Q.; Qu, Y.-H.; Fu, L.; Cui, G.-H. An unprecedented binodal (4,6)-connected Co(II) MOF as dual-responsive luminescent sensor for detection of acetylacetone and Hg2+ ions. Inorg. Chem. Commun. 2020, 118, 108013.
  102. Sun, X.; Yang, P.; Hou, G.; Wei, J.; Wang, X.; Yang, D.; Zhang, X.; Dong, H.; Zhang, F. Luminescent Functionalised Supramolecular Coordination Polymers Based on an Aromatic Carboxylic Acid Ligand for Sensing Hg2+ Ions Aust. J. Chem. 2017, 70, 786–791.
  103. Li, Q.; Wang, C.; Tan, H.; Tang, G.; Gao, J.; Chen, C.-H. A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury(ii) in biological fluids. RSC Adv. 2016, 6, 17811–17817.
  104. Li, W.-X.; Li, H.-X.; Li, H.-Y.; Chen, M.-M.; Shi, Y.-X.; Lang, J.-P. 1,4-Bis(2-(pyridin-4-yl)vinyl)naphthalene and Its Zinc(II) Coordination Polymers: Synthesis, Structural Characterization, and Selective Luminescent Sensing of Mercury(II) Ion. Cryst. Growth Des. 2017, 17, 3948–3959.
  105. Zhang, S.-R.; Wang, W.; Xu, G.-J.; Yao, C.; Xu, Y.-H.; Su, Z.-M. A fluorescent sensor for selective, sensitive, and recyclable detection of mercury(II) in aqueous solution based on a zinc(II) coordination polymer. Inorg. Chem. Commun. 2018, 89, 73–77.
  106. Gong, W.-J.; Yao, R.; Li, H.-X.; Ren, Z.-G.; Zhang, J.-G.; Lang, J.-P. Luminescent cadmium(ii) coordination polymers of 1,2,4,5-tetrakis(4-pyridylvinyl)benzene used as efficient multi-responsive sensors for toxic metal ions in water. Dalton Trans. 2017, 46, 16861–16871.
  107. Wang, X.; Han, Y.; Han, X.X.; Hou, X.; Wang, J.-J.; Fu, F. Highly selective and sensitive detection of Hg2+, Cr2O72−, and nitrobenzene/2,4-dinitrophenol in water via two fluorescent Cd-CPs. New J. Chem. 2018, 42, 19844–19852.
  108. Fang, Y.-M.; Ye, X.; Xia, L.; Dong, W.-W.; Zhao, J.; Li, D.-S. Four different dimensional Zn(II) coordination polymers as fluorescent sensor for detecting Hg2+, Cr2O72− in aqueous solution. J. Solid State Chem. 2018, 266, 181–188.
  109. Lin, J.; Cheng, Q.; Zhou, J.; Lin, X.; Reddy, R.C.K.; Yang, T.; Zhang, G. Five 3D lanthanide-based coordination polymers with 3,3,6T13 topology: Structures and luminescent sensor for Hg2+ and Pb2+ ions. J. Solid State Chem. 2019, 270, 339–345.
  110. Rachuri, Y.; Parmar, B.; Bisht, K.K.; Suresh, E. Multiresponsive Adenine-Based Luminescent Zn(II) Coordination Polymer for Detection of Hg2+ and Trinitrophenol in Aqueous Media. Cryst. Growth Des. 2017, 17, 1363–1372.
  111. Zhu, H.; Han, C.; Li, Y.-H.; Cui, G.-H. Two new coordination polymers containing long flexible bis(benzimidazole) ligand as luminescent chemosensors for acetylacetone and Hg(II) ions detection. J. Solid State Chem. 2020, 282, 121132.
  112. Ravikumar, A.; Panneerselvam, P.; Morad, N. Metal-Polydopamine Framework as an Effective Fluorescent Quencher for Highly Sensitive Detection of Hg(II) and Ag(I) Ions through Exonuclease III Activity. ACS Appl. Mater. Interfaces 2018, 10, 20550–20558.
  113. Huang, N.-H.; Liu, Y.; Li, R.-T.; Chen, J.; Hu, P.-P.; Young, D.J.; Chen, J.-X.; Zhang, W.-H. Sequential Ag+/biothiol and synchronous Ag+/Hg2+ biosensing with zwitterionic Cu2+-based metal–organic frameworks. Analyst 2020, 145, 2779–2788.
  114. Huang, N.-H.; Li, R.-T.; Fan, C.; Wu, K.-Y.; Zhang, Z.; Chen, J.-X. Rapid sequential detection of Hg2+ and biothiols by a probe DNA-MOF hybrid sensory system. J. Inorg. Biochem. 2019, 197, 110690.
  115. Wu, L.-L.; Wang, Z.; Zhao, S.-N.; Meng, X.; Song, X.-Z.; Feng, J.; Song, S.-Y.; Zhang, H.-J. A Metal-Organic Framework/DNA Hybrid System as a Novel Fluorescent Biosensor for Mercury(II) Ion Detection. Chem. A Eur. J. 2015, 22, 477–480.
  116. Wang, C.; Tang, G.; Tan, H. Colorimetric determination of mercury(II) via the inhibition by ssDNA of the oxidase-like activity of a mixed valence state cerium-based metal-organic framework. Microchim. Acta 2018, 185, 475.
  117. Wu, F.; Ye, J.; Cao, Y.; Wang, Z.; Miao, T.; Shi, Q. Recent advances in fluorescence sensors based on DNA-MOF hybrids. Luminescence 2020, 35, 440–446.
  118. Chen, H.-L.; Li, R.-T.; Wu, K.-Y.; Hu, P.-P.; Zhang, Z.; Huang, N.-H.; Zhang, W.-H.; Chen, J.-X. Experimental and theoretical validations of a one-pot sequential sensing of Hg2+ and biothiols by a 3D Cu-based zwitterionic metal−organic framework. Talanta 2020, 210, 120596.
  119. Wu, X.-J.; Kong, F.; Zhao, C.-Q.; Ding, S.-N. Ratiometric fluorescent nanosensors for ultra-sensitive detection of mercury ions based on AuNCs/MOFs. Analyst 2019, 144, 2523–2530.
  120. Govindaraju, S.; Puthiaraj, P.; Lee, M.-H.; Yun, K. Photoluminescent for Ultrasensitive Detection of Mercury in Water Samples. ACS Omega 2018, 3, 12052–12059.
  121. Marieeswaran, M.; Panneerselvam, P. A magnetic nanoscale metal-organic framework (MNMOF) as a viable fluorescence quencher material for ssDNA and for the detection of mercury ions via a novel quenching-quenching mechanism. RSC Adv. 2020, 10, 3705–3714.
  122. Hu, P.-P.; Liu, N.; Wu, K.-Y.; Zhai, L.-Y.; Xie, B.-P.; Sun, B.; Duan, W.-J.; Zhang, W.-H.; Chen, J.-X. Successive and Specific Detection of Hg2+ and I– by a Biosensor: Experimental and Simulation Studies. Inorg. Chem. 2018, 57, 8382–8389.
  123. Wang, X.; Wang, H.; Guo, L.; Chen, G.; Kong, R.; Qu, F.; Xia, L. Colorimetric detection of Hg(ii) based on the gold amalgam-triggered reductase mimetic activity in aqueous solution by employing nanoparticles. Analyst 2020, 145, 1362–1367.
  124. Zhang, Y.; Song, J.; Pan, Q.; Zhang, X.; Shao, W.; Quan, C.; Li, J. An (Ti)-based multifunctional platform for colorimetric detections of biomolecules and Hg2+. J. Mater. Chem. B 2020, 8, 114–124.
  125. Guo, M.; Chi, J.; Li, Y.; Waterhouse, G.I.N.; Ai, S.; Hou, J.; Li, X. Fluorometric determination of mercury(II) based on dual-emission metal-organic frameworks incorporating carbon dots and gold nanoclusters. Microchim. Acta 2020, 187, 534.
  126. Yang, Y.; Liu, W.; Cao, J.; Wu, Y. On-site, rapid and visual determination of Hg2+ and Cu2+ in red wine by ratiometric fluorescence sensor of metal-organic frameworks and CdTe QDs. Food Chem. 2020, 328, 127119.
  127. Shellaiah, M.; Sun, K.W. Inorganic-Diverse Nanostructured Materials for Volatile Organic Compound Sensing. Sensors 2021, 21, 633.
  128. Zhang, X.; Jiang, Y.; Zhu, M.; Xu, Y.; Guo, Z.; Shi, J.; Han, E.; Zou, X.; Wang, D. Electrochemical DNA sensor for inorganic mercury(II) ion at attomolar level in dairy product using Cu(II)-anchored metal-organic framework as mimetic catalyst. Chem. Eng. J. 2020, 383, 123182.
  129. Salandari-Jolge, N.; Ensafi, A.A.; Rezaei, B. Ultra-sensitive electrochemical aptasensor based on zeolitic imidazolate framework-8 derived Ag/Au core-shell nanoparticles for mercury detection in water samples. Sensors Actuators B Chem. 2021, 331, 129426.
  130. Zhang, X.; Zhu, M.; Jiang, Y.; Wang, X.; Guo, Z.; Shi, J.; Zou, X.; Han, E. Simple electrochemical sensing for mercury ions in dairy product using optimal Cu2+-based metal-organic frameworks as signal reporting. J. Hazard. Mater. 2020, 400, 123222.
  131. Fu, L.; Xie, K.; Wang, A.; Lyu, F.; Ge, J.; Zhang, L.; Zhang, H.; Su, W.; Hou, Y.-L.; Zhou, C.; et al. High selective detection of mercury (II) ions by thioether side groups on metal-organic frameworks. Anal. Chim. Acta 2019, 1081, 51–58.
  132. Qing, M.; Chen, S.; Xie, S.; Tang, Y.; Zhang, J.; Yuan, R. Encapsulation and Release of Recognition Probes Based on a Rigid Three-Dimensional DNA “Nanosafe-box” for Construction of a Electrochemical Biosensor. Anal. Chem. 2020, 92, 1811–1817.
  133. Singh, S.; Numan, A.; Zhan, Y.; Singh, V.; Van Hung, T.; Nam, N.D. A novel highly efficient and ultrasensitive electro-chemical detection of toxic mercury (II) ions in canned tuna fish and tap water based on a copper metal-organic framework. J. Hazard. Mater. 2020, 399, 123042.
  134. Kokkinos, C.; Economou, A.; Pournara, A.; Manos, M.; Spanopoulos, I.; Kanatzidis, M.; Tziotzi, T.; Petkov, V.; Margariti, A.; Oikonomopoulos, P.; et al. 3D-printed lab-in-a-syringe voltammetric cell based on a working electrode modified with a highly efficient Ca-MOF sorbent for the determination of Hg(II). Sens. Actuators B Chem. 2020, 321, 128508.
  135. Zhang, L.; Feng, L.; Li, P.; Chen, X.; Jiang, J.; Zhang, S.; Zhang, C.; Zhang, A.; Chen, G.; Wang, H. Direct Z-scheme photocatalyst of hollow polyhedron constructed by ZIF-67-templated one-pot solvothermal route: A signal-on photoelectrochemical sensor for mercury (II). Chem. Eng. J. 2020, 395, 125072.
  136. Chen, Y.; Bai, X.; Ye, Z. Recent Progress in Heavy Metal Ion Decontamination Based on Metal-Organic Frameworks. Nanomaterials 2020, 10, 1481.
  137. Rezaei Kahkha, M.R.; Daliran, S.; Oveisi, A.R.; Kaykhaii, M.; Sepehri, Z. The Mesoporous Porphyrinic Zirconium Metal-Organic Framework for Pipette-Tip Solid-Phase Extraction of Mercury from Fish Samples Followed by Cold Vapor Atomic Absorption Spectrometric Determination. Food Anal. Methods 2017, 10, 2175–2184.
  138. Hasankola, Z.S.; Rahimi, R.; Shayegan, H.; Moradi, E.; Safarifard, V. Removal of Hg2+ heavy metal ion using a highly stable mesoporous porphyrinic zirconium metal-organic framework. Inorg. Chim. Acta 2020, 501, 119264.
  139. Li, J.; Li, X.; Alsaedi, A.; Hayat, T.; Chen, C. Synthesis of highly porous inorganic adsorbents derived from metal-organic frameworks and their application in efficient elimination of mercury(II). J. Colloid Interface Sci. 2018, 517, 61–71.
  140. Leus, K.; Perez, J.P.H.; Folens, K.; Meledina, M.; Van Tendeloo, G.; Du Laing, G.; Van Der Voort, P. UiO-66-(SH)2 as stable, selective and regenerable adsorbent for the removal of mercury from water under environmentally-relevant conditions. Faraday Discuss. 2017, 201, 145–161.
  141. Li, J.; Liu, Y.; Ai, Y.; Alsaedi, A.; Hayat, T.; Wang, X. Combined experimental and theoretical investigation on selective removal of mercury ions by metal organic frameworks modified with thiol groups. Chem. Eng. J. 2018, 354, 790–801.
  142. Fu, L.; Wang, S.; Lin, G.; Zhang, L.; Liu, Q.; Fang, J.; Wei, C.; Liu, G. Post-functionalization of UiO-66-NH2 by 2,5-Dimercapto-1,3,4-thiadiazole for the high efficient removal of Hg(II) in water. J. Hazard. Mater. 2019, 368, 42–51.
  143. Ding, L.; Luo, X.; Shao, P.; Yang, J.; Sun, D. Thiol-Functionalized Zr-Based Metal-Organic Framework for Capture of Hg(II) through a Proton Exchange Reaction. ACS Sustain. Chem. Eng. 2018, 6, 8494–8502.
  144. Li, M.-Q.; Wong, Y.-L.; Lum, T.-S.; Leung, K.S.-Y.; Lam, P.K.S.; Xu, Z. Dense thiol arrays for metal–organic frameworks: Boiling water stability, Hg removal beyond 2 ppb and facile crosslinking. J. Mater. Chem. A 2018, 6, 14566–14570.
  145. Yang, P.; Shu, Y.; Zhuang, Q.; Li, Y.; Gu, J. A robust MOF-based trap with high-density active alkyl thiol for the super-efficient capture of mercury. Chem. Commun. 2019, 55, 12972–12975.
  146. Lin, D.; Liu, X.; Huang, R.; Qi, W.; Su, R.; He, Z. One-pot synthesis of mercapto functionalized Zr-MOFs for the enhanced removal of Hg2+ ions from water. Chem. Commun. 2019, 55, 6775–6778.
  147. Zhao, M.; Huang, Z.; Wang, S.; Zhang, L.; Zhou, Y. Design of l-Cysteine Functionalized UiO-66 MOFs for Selective Adsorption of Hg(II) in Aqueous Medium. ACS Appl. Mater. Interfaces 2019, 11, 46973–46983.
  148. Liu, F.; Xiong, W.; Feng, X.; Cheng, G.; Shi, L.; Chen, D.; Zhang, Y. Highly recyclable cysteamine-modified acid-resistant MOFs for enhancing Hg (II) removal from water. Environ. Technol. 2019, 41, 1–11.
  149. He, Y.; Hou, Y.-L.; Wong, Y.-L.; Xiao, R.; Li, M.-Q.; Hao, Z.; Huang, J.; Wang, L.; Zeller, M.; He, J.; et al. Improving stability against desolvation and mercury removal performance of Zr(iv)-carboxylate frameworks by using bulky sulfur functions. J. Mater. Chem. A 2017, 6, 1648–1654.
  150. Chen, S.; Feng, F.; Li, S.; Li, X.-X.; Shu, L. Metal-organic framework DUT-67 (Zr) for adsorptive removal of trace Hg2+ and CH3Hg+ in water. Chem. Speciat. Bioavailab. 2018, 30, 99–106.
  151. Liu, Q.; Zhang, Q.; Liu, B.; Ma, J. A new synthesis and adsorption mechanism of ZrO2 based metal-organic frames for efficient removal of mercury ions from aqueous solution. Ceram. Int. 2019, 45, 15720–15724.
  152. Xiong, Y.Y.; Li, J.Q.; Le Gong, L.; Feng, X.F.; Na Meng, L.; Zhang, L.; Meng, P.P.; Luo, M.B.; Luo, F. Using MOF-74 for Hg2+ removal from ultra-low concentration aqueous solution. J. Solid State Chem. 2017, 246, 16–22.
  153. Wang, C.-M.; Lin, Y.-J.; Pan, M.-F.; Su, C.-K.; Lin, T.-Y. A Highly Stable Framework of Crystalline Zinc Phosphite with Selective Removal, Recovery, and Turn-On Sensing Abilities for Mercury Cations in Aqueous Solutions. Chem. Eur. J. 2018, 24, 9729–9734.
  154. Esrafili, L.; Gharib, M.; Morsali, A. The targeted design of dual-functional metal–organic frameworks (DF-MOFs) as highly efficient adsorbents for Hg2+ ions: Synthesis for purpose. Dalton Trans. 2019, 48, 17831–17839.
  155. Wu, Y.; Xu, G.; Wei, F.; Song, Q.; Tang, T.; Wang, X.; Hu, Q. Determination of Hg (II) in tea and mushroom samples based on metal-organic frameworks as solid phase extraction sorbents. Microporous Mesoporous Mater. 2016, 235, 204–210.
  156. Mon, M.; Qu, X.; Ferrando-Soria, J.; Pellicer-Carreño, I.; Sepúlveda-Escribano, A.; Ramos-Fernandez, E.V.; Jansen, J.C.; Armentano, D.; Pardo, E. Fine-tuning of the confined space in microporous metal–organic frameworks for efficient mercury removal. J. Mater. Chem. A 2017, 5, 20120–20125.
  157. Yazdi, M.N.; Yamini, Y.; Asiabi, H.; Alizadeh, A. A metal organic framework prepared from benzene-1,3,5-tricarboxylic acid and copper(II), and functionalized with various polysulfides as a sorbent for selective sorption of trace amounts of heavy metal ions. Microchim. Acta 2018, 185, 525.
  158. Xu, W.-Q.; Lin, C.-C.; Qiu, Y.-X.; He, S.; Jiang, T.; Liu, X.-J.; Xie, L.-J.; Fuhr, O.; Fenske, D.; Jiang, J.-J. A Recoverable Complex with Nitrogen-Rich Double Rings for Hg(II) Sorption. ChemistrySelect 2018, 3, 7592–7595.
  159. Xu, W.-Q.; He, S.; Liu, S.-J.; Liu, X.-H.; Qiu, Y.-X.; Liu, W.-T.; Jiang, L.-C.; Jiang, J.-J. Post-synthetic modification of a metal-organic framework based on 5-aminoisophthalic acid for mercury sorption. Inorg. Chem. Commun. 2019, 108, 107515.
  160. Liang, L.; Chen, Q.; Jiang, F.; Yuan, D.; Qian, J.; Lv, G.; Xue, H.; Liu, L.; Jiang, H.-L.; Hong, M. In situ large-scale construction of sulfur-functionalized metal–organic framework and its efficient removal of Hg(ii) from water. J. Mater. Chem. A 2016, 4, 15370–15374.
  161. Jiang, S.-Y.; He, W.-W.; Li, S.-L.; Su, Z.-M.; Lan, Y.-Q. Introduction of Molecular Building Blocks to Improve the Stability of Metal–Organic Frameworks for Efficient Mercury Removal. Inorg. Chem. 2018, 57, 6118–6123.
  162. Wang, C.; He, C.; Luo, Y.-H.; Su, S.; Wang, J.-Y.; Hong, D.-L.; He, X.-T.; Chen, C.; Sun, B.-W. Efficient mercury chloride capture by ultrathin 2D metal-organic framework nanosheets. Chem. Eng. J. 2020, 379, 122337.
  163. Tian, J.; Shi, C.; Xiao, C.; Jiang, F.; Yuan, D.; Chen, Q.; Hong, M. Introduction of Flexibility into a Metal-Organic Framework to Promote Hg(II) Capture through Adaptive Deformation. Inorg. Chem. 2020, 59, 18264–18275.
  164. Halder, S.; Mondal, J.; Ortega-Castro, J.; Frontera, A.; Roy, P. A Ni-based MOF for selective detection and removal of Hg2+ in aqueous medium: A facile strategy. Dalton Trans. 2017, 46, 1943–1950.
  165. Li, G.-P.; Zhang, K.; Zhang, P.-F.; Liu, W.-N.; Tong, W.-Q.; Hou, L.; Wang, Y.-Y. Thiol-Functionalized Pores via Post-Synthesis Modification in a Metal-Organic Framework with Selective Removal of Hg(II) in Water. Inorg. Chem. 2019, 58, 3409–3415.
  166. Li, K.; Li, J.-J.; Zhao, N.; Xie, T.-T.; Di, B.; Xu, L.-L. Thioether-based recyclable metal-organic frameworks for selective and efficient removal of Hg2+ from water. Dalton Trans. 2019, 48, 17800–17809.
  167. Han, Y.; Zheng, H.; Liu, K.; Wang, H.; Huang, H.; Xie, L.-H.; Wang, L.; Li, J.-R. In-Situ Ligand Formation-Driven Preparation of a Heterometallic Metal-Organic Framework for Highly Selective Separation of Light Hydrocarbons and Efficient Mercury Adsorption. ACS Appl. Mater. Interfaces 2016, 8, 23331–23337.
  168. Mon, M.; Lloret, F.; Ferrando-Soria, J.; Martí-Gastaldo, C.; Armentano, D.; Pardo, E. Selective and Efficient Removal of Mercury from Aqueous Media with the Highly Flexible Arms of a BioMOF. Angew. Chem. Int. Ed. 2016, 55, 11167–11172.
  169. Saleem, H.; Rafique, U.; Davies, R.P. Investigations on post-synthetically modified UiO-66-NH2 for the adsorptive removal of heavy metal ions from aqueous solution. Microporous Mesoporous Mater. 2016, 221, 238–244.
  170. Wu, J.; Zhou, J.; Zhang, S.; Alsaedi, A.; Hayat, T.; Li, J.; Song, Y. Efficient removal of metal contaminants by EDTA modified MOF from aqueous solutions. J. Colloid Interface Sci. 2019, 555, 403–412.
  171. Rouhani, F.; Morsali, A. Fast and Selective Heavy Metal Removal by a Novel Metal-Organic Framework Designed with In-Situ Ligand Building Block Fabrication Bearing Free Nitrogen. Chem. A Eur. J. 2018, 24, 5529–5537.
  172. Hakimifar, A.; Morsali, A. Urea-Based Metal-Organic Frameworks as High and Fast Adsorbent for Hg2+ and Pb2+ Removal from Water. Inorg. Chem. 2019, 58, 180–187.
  173. Mon, M.; Bruno, R.; Tiburcio, E.; Viciano-Chumillas, M.; Kalinke, L.H.G.; Ferrando-Soria, J.; Armentano, D.; Pardo, E. Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water. J. Am. Chem. Soc. 2019, 141, 13601–13609.
  174. Ru, J.; Wang, X.; Wang, F.; Cui, X.; Du, X.; Lu, X. UiO series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: Synthesis, applications and adsorption mechanism. Ecotoxicol. Environ. Saf. 2021, 208, 111577.
  175. Li, H.; Liu, H.; Zhang, J.; Cheng, Y.; Zhang, C.; Fei, X.; Xian, Y. Platinum Nanoparticle Encapsulated Metal-Organic Frameworks for Colorimetric Measurement and Facile Removal of Mercury(II). ACS Appl. Mater. Interfaces 2017, 9, 40716–40725.
  176. Shi, M.; Lin, D.; Huang, R.; Qi, W.; Su, R.; He, Z. Construction of a Mercapto-Functionalized Zr-MOF/Melamine Sponge Composite for the Efficient Removal of Oils and Heavy Metal Ions from Water. Ind. Eng. Chem. Res. 2020, 59, 13220–13227.
  177. Liu, F.; Xiong, W.; Feng, X.; Shi, L.; Chen, D.; Zhang, Y. A novel monolith ZnS-ZIF-8 adsorption material for ultraeffective Hg (II) capture from wastewater. J. Hazard. Mater. 2019, 367, 381–389.
  178. Nosike, E.I.; Jiang, Z.; Miao, L.; Akakuru, O.U.; Yuan, B.; Wu, S.; Zhang, Y.; Zhang, Y.; Wu, A. A novel hybrid nanoadsorbent for effective Hg2+ adsorption based on zeolitic imidazolate framework (ZIF-90) assembled onto poly acrylic acid capped Fe3O4 nanoparticles and cysteine. J. Hazard. Mater. 2020, 392, 122288.
  179. Huang, L.; He, M.; Chen, B.; Hu, B. A designable magnetic MOF composite and facile coordination-based post-synthetic strategy for the enhanced removal of Hg2+ from water. J. Mater. Chem. A 2015, 3, 11587–11595.
  180. Liang, L.; Liu, L.; Jiang, F.; Liu, C.; Yuan, D.; Chen, Q.; Wu, D.; Jiang, H.-L.; Hong, M. Incorporation of In2S3 Nanoparticles into a Metal-Organic Framework for Ultrafast Removal of Hg from Water. Inorg. Chem. 2018, 57, 4891–4897.
  181. Ke, F.; Jiang, J.; Li, Y.; Wan, X.; Ko, S. Highly selective removal of Hg 2+ and Pb2+ by thiol-functionalized Fe3O4@metal-organic framework core-shell magnetic microspheres. Appl. Surf. Sci. 2017, 413, 266–274.
  182. Sun, D.T.; Peng, L.; Reeder, W.S.; Moosavi, S.M.; Tiana, D.; Britt, D.K.; Oveisi, E.; Queen, W.L. Rapid, Selective Heavy Metal Removal from Water by a Metal-Organic Framework/Polydopamine Composite. ACS Cent. Sci. 2018, 4, 349–356.
  183. Abdollahi, N.; Akbar Razavi, S.A.; Morsali, A.; Hu, M.-L. High capacity Hg(II) and Pb(II) removal using MOF-based nanocomposite: Cooperative effects of pore functionalization and surface-charge modulation. J. Hazard. Mater. 2020, 387, 121667.
  184. Liu, Y.; Li, H.; Liu, J. Theoretical prediction the removal of mercury from flue gas by MOFs. Fuel 2016, 184, 474–480.
  185. Tang, H.; Fang, H.; Duan, Y.; Sholl, D.S. Predictions of Hg0 and HgCl2 Adsorption Properties in UiO-66 from Flue Gas Using Molecular Simulations. J. Phys. Chem. C 2019, 123, 5972–5979.
  186. Zhao, S.; Mei, J.; Xu, H.; Liu, W.; Qu, Z.; Cui, Y.; Yan, N. Research of mercury removal from sintering flue gas of iron and steel by the open metal site of Mil-101(Cr). J. Hazard. Mater. 2018, 351, 301–307.
  187. Dong, L.; Huang, Y.; Liu, L.; Liu, C.; Xu, L.; Zha, J.; Chen, H.; Liu, H. Investigation of Elemental Mercury Removal from Coal-Fired Boiler Flue Gas over MIL101-Cr. Energy Fuels 2019, 33, 8864–8875.
  188. Chen, D.; Zhao, S.; Qu, Z.; Yan, N. Cu-BTC as a novel material for elemental mercury removal from sintering gas. Fuel 2018, 217, 297–305.
  189. Zhou, J.; Cao, L.; Wang, Q.; Tariq, M.; Xue, Y.; Zhou, Z.; Sun, W.; Yang, J. Enhanced Hg0 removal via α-MnO2 anchored to MIL-96(Al). Appl. Surf. Sci. 2019, 483, 252–259.
  190. Zhang, X.; Shi, Q.; Shen, B.; Hu, Z. MIL-100(Fe) supported Mn-based catalyst and its behavior in Hg0 removal from flue gas. J. Hazard. Mater. 2020, 381, 121003.
  191. Yang, Z.; Li, H.; Yang, J.; Feng, S.; Liu, X.; Zhao, J.; Qu, W.; Li, P.; Feng, Y.; Lee, P.-H.; et al. Nanosized Copper Selenide Functionalized Zeolitic Imidazolate Framework-8 (CuSe/ZIF-8) for Efficient Immobilization of Gas-Phase Elemental Mercury. Adv. Funct. Mater. 2019, 29, 1807191.
  192. Yang, J.; Zhu, W.; Qu, W.; Yang, Z.; Wang, J.; Zhang, M.; Li, H. Selenium Functionalized Metal–Organic Framework MIL-101 for Efficient and Permanent Sequestration of Mercury. Environ. Sci. Technol. 2019, 53, 2260–2268.
  193. Zhao, S.; Chen, D.; Xu, H.; Mei, J.; Qu, Z.; Liu, P.; Cui, Y.; Yan, N. Combined effects of Ag and UiO-66 for removal of elemental mercury from flue gas. Chemosphere 2018, 197, 65–72.
  194. Zhang, X.; Shen, B.; Shen, F.; Si, M.; Yuan, P. The behavior of the manganese-cerium loaded metal-organic framework in elemental mercury and NO removal from flue gas. Chem. Eng. J. 2017, 326, 551–560.
  195. Rudd, N.D.; Wang, H.; Fuentes-Fernandez, E.M.A.; Teat, S.J.; Chen, F.; Hall, G.; Chabal, Y.J.; Li, J. Highly Efficient Luminescent Metal-Organic Framework for the Simultaneous Detection and Removal of Heavy Metals from Water. ACS Appl. Mater. Interfaces 2016, 8, 30294–30303.
  196. Zhang, L.; Wang, J.; Du, T.; Zhang, W.; Zhu, W.; Yang, C.; Yue, T.; Sun, J.; Li, T.; Wang, J. NH2-MIL-53(Al) Metal–Organic Framework as the Smart Platform for Simultaneous High-Performance Detection and Removal of Hg2+. Inorg. Chem. 2019, 58, 12573–12581.
  197. Radwan, A.; El-Sewify, I.M.; Shahat, A.; Azzazy, H.M.E.; Khalil, M.M.H.; El-Shahat, M.F. Multiuse Al-MOF Chemosensors for Visual Detection and Removal of Mercury Ions in Water and Skin-Whitening Cosmetics. ACS Sustain. Chem. Eng. 2020, 8, 15097–15107.
  198. Shahat, A.; Elsalam, S.A.; Herrero-Martínez, J.M.; Simó-Alfonso, E.F.; Ramis-Ramos, G. Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF. Sens. Actuators B Chem. 2017, 253, 164–172.
  199. Esrafili, L.; Gharib, M.; Morsali, A. Selective detection and removal of mercury ions by dual-functionalized metal-organic frameworks: Design-for-purpose. New J. Chem. 2019, 43, 18079–18091.
  200. Xiong, Y.; Su, L.; Yang, H.; Ye, F.; Zhang, P. Fabrication of copper sulfide using a Cu-based metal organic framework for the colorimetric determination and the efficient removal of Hg2+ in aqueous solutions. New J. Chem. 2015, 39, 9221–9227.
  201. Moradi, E.; Rahimi, R.; Safarifard, V. Porphyrinic zirconium-based MOF with exposed pyrrole Lewis base site as an efficient fluorescence sensing for Hg2+ ions, DMF small molecule, and adsorption of Hg2+ ions from water solution. J. Solid State Chem. 2020, 286, 121277.
  202. Yang, H.; Peng, C.; Han, J.; Song, Y.; Wang, L. Three-dimensional macroporous Carbon/Zr-2,5-dimercaptoterephthalic acid metal-organic frameworks nanocomposites for removal and detection of Hg(II). Sens. Actuators B Chem. 2020, 320, 128447.
  203. Shellaiah, M.; Thirumalaivasan, N.; Sun, K.W.; Wu, S.-P. A pH cooperative strategy for enhanced colorimetric sensing of Cr(III) ions using biocompatible L-glutamic acid stabilized gold nanoparticles. Microchem. J. 2021, 160, 105754.
  204. Shellaiah, M.; Simon, T.; Thirumalaivasan, N.; Sun, K.W.; Ko, F.-H.; Wu, S.-P. Cysteamine-capped gold-copper nanoclusters for fluorometric determination and imaging of chromium(VI) and dopamine. Microchim. Acta 2019, 186, 788.
  205. Shellaiah, M.; Chen, Y.-C.; Simon, T.; Li, L.-C.; Sun, K.W.; Ko, F.-H. Effect of Metal Ions on Hybrid Graphite-Diamond Nanowire Growth: Conductivity Measurements from a Single Nanowire Device. Nanomaterials 2019, 9, 415.
  206. Shellaiah, M.; Sun, K.W. Review on Nanomaterial-Based Melamine Detection. Chemosensors 2019, 7, 9.
  207. He, J.; Wu, X.; Long, Z.; Hou, X. Fast and sensitive fluorescent and visual sensing of cysteine using Hg-metalated PCN-222. Microchem. J. 2019, 145, 68–73.
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