CO2 Storage in Shale Reservoirs

As a new “sink” of CO

2

permanent storage, the depleted shale reservoir is very promising compared to the deep saline aquifer. To provide a greater understanding of the benefits of CO

2

 storage in a shale reservoir, a comparative study is conducted by establishing the full-mechanism model, including the hydrodynamic trapping, adsorption trapping, residual trapping, solubility trapping as well as the mineral trapping corresponding to the typical shale and deep saline aquifer parameters from the Ordos basin in China. The results show that CO

2

 storage in the depleted shale reservoir has merits in storage safety by trapping more CO

2

 in stable immobile phase due to adsorption and having gentler and ephemeral pressure perturbation responding to CO

2

 injection. The effect of various CO

2

 injection schemes, namely the high-speed continuous injection, low-speed continuous injection, huff-n-puff injection and water alternative injection, on the phase transformation of CO

2

 in a shale reservoir and CO

2

-injection-induced perturbations in formation pressure are also examined. With the aim of increasing the fraction of immobile CO

2

while maintaining a safe pressure-perturbation, it is shown that an intermittent injection procedure with multiple slugs of huff-n-puff injection can be employed and within the allowable range of pressure increase, and the CO

2

 injection rate can be maximized to increase the CO

2

 storage capacity and security in shale reservoir.

CO2 geological storage,;shale,;phase transformation,;pressure perturbation,;injection schemes
  1. Introduction

1. Introduction

The capture of anthropogenic carbon dioxide (CO

2

) from industrial or other emission sources and its long-term storage in geological formations to limit its emission into the atmosphere is referred as geological carbon storage (GCS) [1]. GCS is regarded as one of the most effective technologies to reduce the greenhouse gas emissions from the combustion of fossil fuels. Besides the conventional CO

2 storage sites in the deep saline aquifers, depleted oil and gas reservoirs, and un-minable coal seams [2,3], the depleted shale reservoir is also rapidly becoming a new and potentially promising CO

storage sites in the deep saline aquifers, depleted oil and gas reservoirs, and un-minable coal seams [2][3], the depleted shale reservoir is also rapidly becoming a new and potentially promising CO

2 storage option because of the booming production of the unconventional shale gas [4,5].

storage option because of the booming production of the unconventional shale gas [4][5].

Interest in CO

2

 storage in shale reservoirs has grown recently because shale is widely reported to possess higher affinity to CO

2

 than CH

4

 and has huge potential for CO

2 adsorption trapping. For example, Heller and Zoback [6], Kang et al. [7], and Zhang [8] all tested the CO

adsorption trapping. For example, Heller and Zoback [6], Kang et al. [7], and Zhang [8] all tested the CO

2

/CH

4

 adsorption capacity of shale from different places in the world and demonstrated that the CO

2

 adsorption capacity to shale was greater than that of CH

4

 under surface condition. Several feasibility studies for CO

2

 storage in shale reservoirs have demonstrated that CO

2

 can be trapped in the shale matrix and at the same time can significantly enhance the methane recovery by CO

2

/CH

4 competitive adsorption [9]. Liu et al. [10] indicated that 95% of injected CO

competitive adsorption [9]. Liu et al. [10] indicated that 95% of injected CO

2

 can be permanently sequestered in the Devonian and Mississippian New Albany shale with gas adsorption being the dominant storage mechanism. A large storage capacity of CO

2

 in shale reservoirs has also been evaluated and it was estimated that the CO

2

 storage capacity of the Marcellus shale in the eastern United States alone could store between 10.4 and 18.4 Gt of CO

2 between now and 2030 [11].

between now and 2030 [11].

In GCS, it is very important to study the CO

2

 plume evolution and migration as well as different phase transformations due to various trapping mechanisms for the sake of security. In a shale reservoir, there is one more trapping mechanism for CO

2

 compared to those in the deep saline aquifers, and that is the adsorption trapping of CO

2

 to the surface of the host rock simultaneously promoting the desorption of the in-place CH

4 [12]. It is important to recall here the other well-known trapping mechanisms, namely the hydrodynamic trapping, solution trapping, mineral trapping and residual or capillary trapping. Furthermore, although all these trapping mechanisms may take effect within a given reservoir, they occur at different time scales. Moreover, only a few of these mechanisms contribute significantly to plume immobilization in time scales comparable to the injection times or arguably even over the duration of the site stewardship. On shorter time scales, hydrodynamic trapping, residual, and adsorption trapping are the dominant mechanisms that play an important role in plume immobilization in the reservoir [13,14,15,16]. In the long-term, a significant amount of CO

[12]. It is important to recall here the other well-known trapping mechanisms, namely the hydrodynamic trapping, solution trapping, mineral trapping and residual or capillary trapping. Furthermore, although all these trapping mechanisms may take effect within a given reservoir, they occur at different time scales. Moreover, only a few of these mechanisms contribute significantly to plume immobilization in time scales comparable to the injection times or arguably even over the duration of the site stewardship. On shorter time scales, hydrodynamic trapping, residual, and adsorption trapping are the dominant mechanisms that play an important role in plume immobilization in the reservoir [13][14][15][16]. In the long-term, a significant amount of CO

2

 will be trapped through dissolving into the formation water (solubility trapping) and finally being permanently stored in mineral phase by reacting with the host rock (mineral trapping), which gradually begins to contribute to CO

2 plume immobilization in shale reservoirs [12].

plume immobilization in shale reservoirs [12].

  1. Results and Discussion

2. Results and Discussion

Table 1 shows the simulation cases considered and analyzed in this paper.

      Table 1

Description of simulation cases 

Case description

Gas adsorption

CO2 injection rate/(m3/day)*

CO2 injection period /(year)

CO2 injection scheme

Lithology

Case 1

/

4000

30

Continuous injection

LJG sand

Case 2

R

4000

30

Continuous injection

YC shale

Case 3

R

2000

60

Continuous injection

YC shale

Case 4

R

4000

30

Huff-n-puff injection

YC shale

Case 5

R

4000

30

Water alternating gas injection

YC shale

* 4000 m

3

/day ≈ 0.09 kg/s

2.1. Comparison of CO2 Storage in Shale and Deep Saline Aquifer

The cumulative levels of CO

2

trapped with different mechanisms for the Yanchang (YC) shale and  Liujiagou (LJG) sand from Shenhua saline aquifer in Ordos basin in China at the same CO

2

injection rate are compared and plotted in

Figure 1

. It can be observed that with a total amount of 1861.55 Mmoles (1861.55 × 10

6

 moles) of CO

2

 injected in 30 years, 656.59 Mmoles was in the free phase, 474.66 Mmoles was adsorbed, 102.03 Mmoles was trapped in residual phase, 179.12 Mmoles was dissolved in the formation water, and the remaining 458.06 Mmoles was trapped as mineralized CO

2

 in shale at 500 years. For sand, 1075.36 Mmoles was in the free phase, 279.44 Mmoles was trapped through hysteresis, 155.88 Mmoles was in dissolution phase, and the rest 353.82 Mmoles was stored through CO

2

–water–shale reactions. Within a timescale of <200 years, sand reservoir possesses priority in trapping CO

2

 not only in the free gas phase and residual phase but also in the dissolution phase as well as the mineral phase. As time goes on, the superiority of sand trapping of CO

2

 in the stable chemical phase is overwhelmed by shale.

Figure 1. (a,b) Cumulative CO2 storage under different mechanisms in shale and sand; (c,e) free CO2 distributions for case 1 (YC shale) at 30 years and 500 years; (d,f) free CO2 distributions for case 2 (LJG sand) at 30 years and 500 years.

Figure 1

 also displays the CO

2

 plume distribution at 30 years and 500 years for the sand and shale reservoir. Due to the high permeability of LJG sand compared to the YC shale, both CO

2

 and pressure migrate faster along the horizontal plane, and this phenomenon is discussed in detail later. However, the pressure perturbation induced by CO

2

 injection in the shale reservoir was constrained close to the stimulation zone. Once injection stopped, the in-place groundwater invaded the gas in the pores and micro-fractures and created the accumulation of CO

2

 in residual phase. The larger CO

2

 plume in the sand reservoir increases the interfacial area for subsequent residual trapping, dissolution and even the reaction with minerals (

Figure 1(

a, b)).

Although both reservoirs experience a pressure reduction response to injection stoppage, the pressure variation is neglected within the CO

2

 plume for the sand reservoir and the fluid flow is dominated by diffusion in horizontal plane. However, there is nearly a 17-MPa pressure difference between the injection site and the margin of the CO

2

 plume in shale; both advection and diffusion control the CO

2

 migration. As a result, the CO

2

 plume still expands outward for the shale but remains nearly unchanged for the saline aquifer after injection stops. It leads to wider CO

2

 plume at 500 years for shale than for the sand reservoir. The pressure perturbation caused by CO

2

 plume evolution combined with the transformation of the adsorbed phase into the dissolved phase causes the phenomenon of shale having more chemical trapping of CO

2

 in the longer term.

The various CO

2

 storage mechanisms have different operating time frames, among which the hydrodynamic and adsorption trapping take effect immediately after the CO

2

 injection, while the residual gas, dissolution and particularly the mineral trapping mechanisms are a slow process, and can occur over a time scale of centuries to millennia. Instead, these three mechanisms play an essential role in increasing the security and safety of CO

2

 geological storage [

3

]. In addition, different trapping mechanisms are strongly coupled and are competitive with each other, and different phases of CO

2

 in the reservoir inter-convert dynamically. To improve CO

2

 storage security as well as efficiency, the CO

2

 injection strategy should be optimized based on the idea of expanding CO

2

 plume and decrease in the percentage of CO

2

 in the free gaseous phase.

2.2. Effect of CO2 Injection Rate on CO2 Storage in Shale

As stated previously, to enhance the CO

2

 storage security in a shale reservoir by constraining the capacity of free and mobile-phase CO

2

 and to maintain a relatively gentle pressure perturbation, the CO

2

 injection strategy should be precisely designed and optimized. The effects of the CO

2

injection rate on the overall performance of the sequestration project are investigated first. We do so by comparing case 2 and case 3. The same amount of CO

2

 is injected in both cases, but over a period of 30 years in case 2 and over a period of 60 years in case 3.

The cumulative CO

2

 in different phases for both cases (case 2 and case 3) is shown in 

Figure 2(a,b)

. By comparing the deviation of the cumulative CO

2

 stored in different phases for case 2 and case 3 at 500 years shown in 

Table 2

, the change in residual trapping is most dramatic with the change in the injection rate. It can be seen from 

Table 2

 that there was a 19.52% reduction in the residual trapping of CO

2

 due to a decrease in the CO

2

 injection rate. In addition, case 3 also has more CO

2

 in the mobile free phase than case 2; the deviation is 38.56 Mmoles at 500 years. More CO

2

 exists in the free phase to promote its horizontal migration. This result is also supported by the profile of the gas saturation in the fractures of the shale reservoir as shown in 

Figure 2(c–h)

. This profile clearly shows that the free-phase CO

2

 migrates further horizontally at higher CO

2

 injection rate especially during the period of CO

2

 injection.

Figure 2. (a,b) Cumulative CO2 storage under different mechanisms at different CO2 injection rates; (c,e,g) free CO2 distributions for case 2 at 30 years, 100 years and 500 years; and (d,f,h) free CO2 distributions for case 3 at 30 years, 100 years and 500 years.

Table 2.

 Comparison of CO

2

 amount in different phases for case 2 and case 3.

 

Cumulative CO

2 Trapped under Different Mechanisms/(106 moles)

Case

Hydrodynamic Trapping

Adsorbed Trapping

Residual Trapping

Dissolution Trapping

Mineral Trapping

Case2

656.59

474.66

102.03

179.12

458.06

Case3

695.15

472.18

82.11

177.39

443.53

Deviation

5.87%

−0.52%

−19.52%

−0.97%

3.17%

2.3. Effect of Huff-N-Puff Injection and Water Alternating Gas Injection



Finally, we investigate the performance of the CO

Finally, we investigate the performance of the CO

2

 sequestration project using the huff-n-puff injection scheme and the injection of alternating slugs of water and CO

2

 scheme, which are widely used in the oil/gas industry to enhance oil and gas production. We compare the results of case 2, case 4 and case 5. In all the three cases, CO

2

 is injected at a rate of 4000 m

3

/day over a period of 30 years. In case 2, the injection of CO

2

 is continuous. In case 4, CO

2

is first injected for 15 years, then the well is shut-down and soaked for five years, and finally the well is opened again and injected for another 15 years. In case 5, the injection scheme is as follows: CO

2

 is first injected at a rate of 4000 m

3

/day for 15 years, water is then injected at a rate of 50 m

3

/day for 5 years, and finally the CO

2

 is injected at the rate of 4000 m

3

/day for another 15 years.

As shown in 

Figure 3

, for the huff-n-puff injection scheme, the addition of CO

2

 soaking time has a limited impact on the performance of CO

2

 storage in a shale reservoir compared to the continuous injection, especially for long-term CO

2

 storage. However, at the beginning, the amount of free CO

2

 increases while the immobile CO

2

 in residual as well as the dissolved phase decreases for the huff-n-puff injection scheme, which is not beneficial for the storage safety of CO

2

. On the other hand, the water alternating gas injection scheme can somehow reduce the free-phase CO

2

 as well as the adsorbed-phase CO

2

 by enhancing the CO

2

 dissolution into the formation water and trapping it in the micro-pores in the residual phase within the timescale of 300 years. However, with the continual ex-solution of CO

2

 from formation water in the longer term, the CO

2

 reaction with the host rock is also prohibited.

Figure 3.

 Cumulative CO

2

 storage in different storage mechanisms using various CO

2

 injection schemes. (

a

): gas phase;(

b

): adsorbed phase; (

c

): dissolved and residual phase; (

d

): mineral phase)

Figure 4

 shows the free-phase CO

2

 distributions for case 2, case 4 and case 5 at 30 years, 100 years and 500 years. It can be observed that, for case 2 and case 4, although the addition of soaking time for CO

2

 injection can hinder the gaseous CO

2

 migration in the horizontal direction, once injection stops, the migration rate is accelerated and the mobile CO

2

 can even move faster than in the case of the continuous injection scheme. The gaseous CO

2

 front in Y direction at 500 years arrives at 600 m for the huff-n-puff scenario but only at nearly 580 m for the continuous injection scenario. On the other hand, the water alternating gas injection scheme (case 5) can apparently decrease the capacity of mobile CO

2

 during the whole period of CO

2

 storage.

Figure 4.

 Free CO

2

 distributions for case 2, case 4 and case 5 at 30, 100 and 500 years. (

a

,

b

,

c

) compare the gas phase CO

2

 distribution of continuous injection scenario at 30 yrs, 100 yrs and 500 yrs, respectively; (

d

,

e

,

f

) show the gas phase CO

2

 distribution of huff-n-puff injection scenario at 30 yrs, 100 yrs and 500 yrs; (

g

,

h

,

i

) give gas phase CO

2

 distribution of water alternative injection scenario at 30 yrs, 100 yrs and 500 yrs.).

2.4. Pressure Perturbation Induced by CO2 Injection

The performance of CO

2

 storage in the subsurface is highly dependent on the pressure evolution in the formation. The adsorptive behavior of gas onto an organic substrate is largely dependent on pressure. Although there are different types of adsorption models that can be used to describe the CO

2 adsorptive behavior to shale, for example the Langmuir model used for the New Albany shale [17] and the Devonian shale from the Kentucky [5], and the BET-type adsorption of CO

adsorptive behavior to shale, for example the Langmuir model used for the New Albany shale [17] and the Devonian shale from the Kentucky [5], and the BET-type adsorption of CO

2 onto Barnett shale [18], they all show that the CO

onto Barnett shale [18], they all show that the CO

2

 adsorption capacity is a function of ambient pressure. The CO

2 dissolution into the formation water is also largely impacted by pressure. Xu et al. [19] indicate that the pressure variation in the reservoir can affect the dissolution of CO

dissolution into the formation water is also largely impacted by pressure. Xu et al. [19] indicate that the pressure variation in the reservoir can affect the dissolution of CO

2

 into the formation brine. As the volume of dissolved CO

2

 changes, the original chemical equilibrium between CO

2

 (aq.), H

2

CO

3

, and HCO

3

 can be re-established and the mineral reactions will also change accordingly.

Furthermore, pressure variation is also a cause for the change in residual trapping. The non-wetting gas to invade the smaller pores is driven by the higher formation pressure, and the snap-off also results in the increase in macroscopic trapping that occurs readily in smaller pores during imbibition. On the other hand, the gravity effect impacts the displacement pattern of water by CO

2 for low capillary entry pressure. Compared with high-viscosity fluid, the low-viscosity gas can form more stable paths when penetrating the high permeability regions of the porous medium, and only the largest pores can be invaded to lead to reduced snap-off during an eventual imbibition process [15].

for low capillary entry pressure. Compared with high-viscosity fluid, the low-viscosity gas can form more stable paths when penetrating the high permeability regions of the porous medium, and only the largest pores can be invaded to lead to reduced snap-off during an eventual imbibition process [15].

Figure 5

 shows the pressure variation at observation point #1 (X = 275 m, Y = 375 m), which is located at the injection site for case 1, case 2, case 3, case 4 and case 5. The drastic pressure build-up induced by CO

2

 injection in the LJG sand is larger and more lasting compared with the YC shale, which displayed with a rapid speed of pressure up and down (

Figure 5

a). The higher permeability not only enhances the fluid penetration into the rock pores and fractures, but also increases the pressure transmission through the reservoir. The pressure perturbation was constrained within the stimulation zone for the shale reservoir; however, the pressure variation was extended to the whole simulation domain for the sand cases and decreased very slowly responding to the injection well shut-in. The significant pressure deviation between the injection site and the surrounding area was the cause of CO

2

 plume expansion within the shale reservoir and also increased the interfacial area for subsequent CO

2

 dissolution and mineral trapping.

Figure 5.

 Pressure evolution at observation point # 1 (X = 275 m, Y = 375 m) for different cases. (

a

) compares the pressure perturbation of continuous injection scenario of shale and sand and also the influence of injection rate; (

b

) shows the pressure build-up of continuous injection scenario, huff-n-puff injection scenario and water alternate injection scenario of shale reservoir).

The pressure build-up in case 3 at the injection point is smaller than in case 2, which significantly weakens the residual trapping, as shown in 

Table 2

. The pressure decrease also leads to the release of CO

2

from the formation water, which combined with gas desorption causes more CO

2

to exist in the free phase. Considering pressure perturbation induced by the three CO

2

 injection schemes (as shown in 

Figure 5

b), although the water alternating gas injection scheme can increase the CO

2

 storage security in a shale reservoir by trapping more CO

2

 in the immobile phase, it induces large pressure build-up during water injection.

2.5. Implication to CO2 Storage Safety and Stability

Due to the high diffusivity of gaseous or supercritical CO

2

, the free-phase CO

2 is generally believed to be in the unstable phase, which can easily migrate into the preferential pathways such as natural or artificial fracture, unfolded fault and abandoned wells and leak from the storage site. Bachu et al. [3] state that the residual-gas trapping, dissolution, and mineralization of CO

is generally believed to be in the unstable phase, which can easily migrate into the preferential pathways such as natural or artificial fracture, unfolded fault and abandoned wells and leak from the storage site. Bachu et al. [3] state that the residual-gas trapping, dissolution, and mineralization of CO

2

 are essential mechanisms in increasing the security and safety of geological storage of CO

2

 in a saline aquifer after cessation of injection as less and less CO

2

 remains in the free, mobile phase over time. It is similar for CO

2

 storage in a shale reservoir. 

Figure 6

 compares the CO

2

 storage security evolution with time for LJG sand and YC shale. It can be seen that the CO

2

 storage security increases with time both for shale and sand because more and more CO

2

 gets stored as a trapped phase over time. Although LJG sand possesses the advantage in trapping more CO

2

 in the residual, dissolution as well as mineral phase in the short term, this merit is overwhelmed by YC shale as time goes on. Besides, more than 20% of gaseous CO

2

 is trapped in the adsorbed phase; the overall unstable mobile-phase CO

2

 in the YC shale reservoir is significantly less than the LJG sand, which indicates that shale shows superiority in security of CO

2

 storage over saline aquifer.

Figure 6.

 Storage security of CO

2

 in (

a

) a deep saline aquifer and (

b

) in a depleted shale reservoir.

  1. Conclusions

3. Conclusions

This study presents a comprehensive analysis of the potential of CO

2

 storage in a shale reservoir based on the geological parameters of Yang Chang (YC) shale in the Ordos basin of China by taking into account the Darcy and diffusive flow, gas sorption/desorption, hysteresis effects, CO

2

 dissolution, and CO

2

–water–shale reactions. The advantage and disadvantage of CO

2

 storage in YC shale are analyzed by comparing them with the CO

2

 storage in LJG sand (saline aquifer) from the Shenhua GCS project in China. To enhance CO

2

 storage security in shale by constraining the capacity of free and mobile-phase CO

2

 and to maintain a relatively gentle pressure perturbation, different injection strategies, including the low rate continuous injection, high rate continuous injection, huff-n-puff injection and the water alternate injection are compared. The results can be summarized as follows:

  • From the point of view of CO2 phase transformation, CO storage in shale can be safer than in saline aquifer by trapping more CO2 in immobile phases, including adsorbed, residual, dissolution and mineral phase with lesser percentage remaining in free mobile phase in longer-term. Although, the saline aquifer has the advantage in trapping more CO2 in the residual, dissolution and mineral phase in the short term.

    From the point of view of CO2 phase transformation, CO2 storage in shale can be safer than in saline aquifer by trapping more CO2 in immobile phases, including adsorbed, residual, dissolution and mineral phase with lesser percentage remaining in free mobile phase in longer-term. Although, the saline aquifer has the advantage in trapping more CO2 in the residual, dissolution and mineral phase in the short term.

    2
  • The pressure perturbation induced by CO2 injection in the saline aquifer is longer lasting and generally larger than in the shale reservoir. The pressure build-up in shale can be rapidly released when CO2 injection is stopped.

    The pressure perturbation induced by CO2 injection in the saline aquifer is longer lasting and generally larger than in the shale reservoir. The pressure build-up in shale can be rapidly released when CO2 injection is stopped.

  • Although the water alternating injection scheme can significantly increase the dissolution and residual phase of CO2 in short to middle term, the pressure build-up caused by water injection is more drastic than other schemes. For the aim of increasing the fraction of immobile CO storage capacity and security in a shale reservoir.

    Although the water alternating injection scheme can significantly increase the dissolution and residual phase of CO2 in short to middle term, the pressure build-up caused by water injection is more drastic than other schemes. For the aim of increasing the fraction of immobile CO2 while maintaining a safe pressure-perturbation, the intermittent injection procedure with multiple slugs of huff-n-puff injection can be employed to replace the continuous CO

    2 while maintaining a safe pressure-perturbation, the intermittent injection procedure with multiple slugs of huff-n-puff injection can be employed to replace the continuous CO

    2

    2 injection. Within the allowable range of pressure increase, the CO2 injection rate can be maximized to increase the CO

     injection. Within the allowable range of pressure increase, the CO2 injection rate can be maximized to increase the CO2 storage capacity and security in a shale reservoir.

    2

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References

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