Microbeads are solid, approximately spherical particles with diameters between one micrometre and one millimetre, distinguished from irregular powders by sphericity and a narrow size distribution rather than by composition [1]. Glass grades are drawn and milled, while polymer microbeads are produced by emulsion, suspension or dispersion polymerisation, in which monomer droplets or swollen particles set into spheres [2]. Diameter, density and surface chemistry are the defining descriptors, since buoyancy in water and retention on a filter both follow from them [3]. Particles of this size range are classed with microplastics when the polymer resists degradation, and that persistence separates them from mineral or glass beads of equal diameter [3]. Encapsulation of a colloidal core within a polymeric bead adds an internal phase without changing the outer geometry [2].
Synthesis and properties of polymers·Polymers and Plastics·Materials Science·Physical Sciences