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Lithium Batteries: Comparison
Please note this is a comparison between Version 1 by Jack Zhong and Version 2 by Jack Zhong.

Lithium batteries are rechargeable cells in which lithium ions move between a host negative electrode and a lithium-transition-metal oxide or phosphate positive electrode through a non-aqueous electrolyte, the charge being balanced by electrons in the external circuit. The term covers several chemistries; the lithium-ion version, in which lithium stays in an inserted form at both electrodes, is the one that dominates, and its position rests on a combination of high cell voltage, energy density and long cycle life rather than on any single property [1]. Capacity loss over time is not caused by one mechanism but by several acting together: growth of the surface film on the negative electrode, loss of cyclable lithium, mechanical damage to the electrode coating and, at the positive electrode, transition-metal dissolution and structural change [2]. Electrode materials are chosen against that background, lithium titanate being a case where a higher operating potential is accepted in exchange for almost no volume change and a very long life [3]. Silicon offers roughly ten times the capacity of graphite but expands on lithiation, so it is taken in nanostructured form [4]. Mixed transition-metal oxides store charge by conversion and have been examined in fibrous morphologies [5]. Safety under abuse and the cost of the electrolyte remain the outstanding concerns.

  • lithium-ion battery
  • insertion electrode
  • solid electrolyte interphase
  • graphite anode
  • energy density
  • capacity fade

 Advanced Battery Materials and Technologies·Electrical and Electronic Engineering·Engineering·Physical Sciences

 

References

  1. Liu, R.Y. Recent Progress of Anode and Cathode Materials for Lithium Ion Battery. Materials Science Forum 2021, 1027, 69-75. [CrossRef]
  2. Agubra, V.; Fergus, J. Lithium Ion Battery Anode Aging Mechanisms. Materials 2013, 6, 1310-1325. [CrossRef]
  3. Yi, T.; Bing, X. Research Progress on Lithium Titanate as Anode Material in Lithium-ion Battery. Journal of Inorganic Materials 2018, 33, 475. [CrossRef]
  4. LI, J.W.; ZHOU, A.J.; LIU, X.Q.; LI, J.Z. Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery. Journal of Inorganic Materials 2013, 28, 1207-1212. [CrossRef]
  5. Cheng, C. Hierarchical MnCo2O4 micro/nano fibres as a high-performance anode of lithium-ion battery. Materials Letters 2022, 324, 132770. [CrossRef]
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