Topic Review
Copper Biological Active Complexes
Very few biological active Cu(II) complexes entered in clinical trials as result of poor water solubility and lipophilicity, low stability as well as in vivo inactivation. Their pharmacological and/or oral administration profile can be improved either by physically encapsulation or by conjugation to an organic matrix via a moiety able to coordinate Cu(II). As result, a large variety of species were developed as delivery carriers such as liposomes, synthetic or natural polymers or dendrimers.
  • 1.4K
  • 28 Dec 2020
Topic Review
Layered Oxide Cathodes
Layered intercalation compounds are the dominant cathode materials for rechargeable Li-ion batteries. In this review, we discuss the topology of the layered structure and explain how the structure (1) sets the voltage slope trends among various alkali ions, (2) is critically limited to certain transition metals due to their electronic structure, and (3) controls the alkali diffusion mechanism. 
  • 1.4K
  • 17 Jun 2021
Topic Review
Ag2O–MnO2/Graphene Oxide Nanocomposite
Catalytic oxidation of alcohol to their analogous carbonyls is one of the key organic reactions in both scientific and industrial applications, with universal production of 10,000 million tons/year of carbonyls in the 20th century. Such as, aldehyde and ketone derivatives are extensively employed as precursors in insecticide, flame-retardant, cosmetic, confectionery, flavoring, pharmaceutical, and beverage industries. 
  • 1.4K
  • 27 Oct 2020
Topic Review
Compounds of Thorium
Many compounds of thorium are known, this is because thorium and uranium are the most stable and accessible actinides and are the only actinides that can be studied safely and legally in bulk in a normal laboratory. As such, they have the best-known chemistry of the actinides, along with that of plutonium, as the self-heating and radiation from them is not enough to cause radiolysis of chemical bonds as it is for the other actinides. While the later actinides from americium onwards are predominantly trivalent and behave more similarly to the corresponding lanthanides, as one would expect from periodic trends, the early actinides up to plutonium (thus including thorium and uranium) have relativistically destabilised and hence delocalised 5f and 6d electrons that participate in chemistry in a similar way to the early transition metals of group 3 through 8: thus, all their valence electrons can participate in chemical reactions, although this is not common for neptunium and plutonium.
  • 1.3K
  • 25 Oct 2022
Topic Review
Water Physisorbed on Natural Clinoptilolite
Infrared spectroscopy (FT-IR) can provide very useful information on the nature of water physisorbed on zeolites. The vibrational characteristics of geomorphic clinoptilolite of natural origin and the water physically adsorbed on it have been investigated. In particular, two types of physisorbed water molecules have been identified by combining the FT-IR analysis with a mild thermal drying treatment (1h at 150°C) of the sample: the loosely-bound water and the tightly-bound water.
  • 1.3K
  • 29 Oct 2020
Topic Review
Rhenium(I) Tricarbonyl Complexes As Photosensitisers
Photodynamic therapy (PDT) is emerging as a significant complementary or alternative approach for cancer treatment. Re(I) tricarbonyl complexes is a new generation of metal-based photosensitisers for PDT that are of great interest in multidisciplinary research.
  • 1.2K
  • 27 Oct 2020
Topic Review
CO2 Hydroboration
The use of CO2 as C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration are summarized.
  • 1.1K
  • 15 Jan 2021
Topic Review
Natural Clinoptilolite
Zeolites are ionic conductors and the cation electrical mobility in zeolites depends on their hydration state; consequently, the water adsorption/desorption process can be simply investigated by measuring the temporal evolution of current intensity in samples exposed to an environment with constant humidity or dry air, respectively. According to this kinetic analysis, a mechanism has been formulated for the water adsorption process able to justify the Lagergren pseudo-first-order kinetics observed for adsorption and the first-order kinetics observed for desorption. In this mechanism water molecules are first attract by the electric field of the cations and then they move at cation-framework interface to maximize the hydrogen bond interactions.
  • 1.1K
  • 28 Oct 2020
Topic Review
Recent Advances of Deep Eutectic Solvents
Deep Eutectic Solvents (DESs) have gained a lot of attention in the last few years because of their vast applicability in a large number of technological processes, the simplicity of their preparation and their high biocompatibility and harmlessness.
  • 1.0K
  • 07 Apr 2022
Topic Review
Glyphosate
Glyphosate [N-(phosphonomethyl) glycine CAS#1071-83-6] is one of the most extensively used broad-spectrum organophosphorus herbicides [1]. It is a widely used herbicide in agriculture against perennial and annual weeds and in silviculture, domestic gardens, and urban areas [2]. 
  • 936
  • 26 Oct 2020
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