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Topic Review
Synthesis of Monoketone Curcuminoids
Curcumin (or diferuloylmethane), a component of Curcuma longa L. rhizomes, displays various biological and pharmacological activities. However, it is poorly bioavailable and unstable in physiological pH. MKCs’ antimicrobial, anticancer, antioxidant, and antiparasitic actions, as well as other less common MKC biological and pharmacological activities, have been shown to be similar or higher than curcumin. The promising biological and pharmacological activities, combined with the attractive synthetic aspects (e.g., good yields and an easiness of product isolation) to obtain MKCs, make this class of compounds an interesting prospect for further antimicrobial, anticancer, and antiparasitic drug discovery.
  • 102
  • 25 Jan 2024
Topic Review
Novel Materials for Semi-Transparent Organic Solar Cells
The rapid development of photovoltaic technology has driven the search for novel materials that can improve the cost-effectiveness and efficiency of solar cells. Organic semiconductors offer unique optical tunability and transparency, allowing customization for the absorption of specific optical spectra like near-infrared radiation. Through the molecular engineering of electron donors and acceptors, these materials can be optimized for targeted optical selectivity. This adaptability enables the development of efficient energy-harvesting devices tailored for specific spectral regions. Consequently, organic semiconductors present a promising avenue for specialized applications such as semi-transparent organic solar cells. 
  • 55
  • 23 Jan 2024
Topic Review
Self-Assembled Monolayer-Based Hole-Transporting Materials
Ever since self-assembled monolayers (SAMs) were adopted as hole-transporting layers (HTL) for perovskite solar cells (PSCs), numerous SAMs for HTL have been synthesized and reported. SAMs offer several unique advantages including relatively simple synthesis, straightforward molecular engineering, effective surface modification using small amounts of molecules, and suitability for large-area device fabrication. 
  • 73
  • 19 Jan 2024
Topic Review
Chlorine in an Organic Molecule
Due to the electronic configuration of the atom and charge of the nucleus, the chlorine in organic molecules can exert a variety of effects. It can depart as a chloride anion in the process of substitution and elimination, facilitates the abstraction of protons and stabilizes generated carbanions, exerts moderate stabilizing effect of carbenes, carbocations and radicals. There are frequent cases where chlorine substituent promotes more than one transformation. 
  • 74
  • 17 Jan 2024
Topic Review
Natural 4-Hydroxy-2-pyrones
4-Hydroxy-2-pyrones as polyketides are widespread in Nature and possess versatile bioactivity that makes them an attractive target for synthesis and modification. Also these pyrones bear several electrophilic and nucleophilic centers that determine their application in organic synthesis.
  • 138
  • 02 Jan 2024
Topic Review
Copper-Catalyzed/Hypervalent Iodine-Mediated Functionalization of Unactivated Compounds
The functionalization of unactivated substrates through the combination of copper catalysts and hypervalent iodine reagents represents a versatile tool in organic synthesis to access various classes of compounds. The hypervalent iodine derivatives can be used simply as oxidizing agents to regenerate the catalytic species or they can associate the functionalization of the starting material.
  • 176
  • 29 Dec 2023
Topic Review
Chiral Hydroxamic Acid Ligands in Asymmetric Synthesis
Chiral hydroxamic acid (HA) and bis-hydroxamic acid (BHA) ligands have made significant contributions to the field of asymmetric synthesis, particularly in the synthesis of natural products. These ligands possess unique molecular structures that allow for exceptional stereochemical control, leading to their widespread use in catalytic systems.
  • 160
  • 19 Dec 2023
Topic Review
Chlorophyll and TiO2
Chlorophyll sensitization can improve the performance of semiconductors like TiO2 in photocatalytic reactions and light-harvesting technologies, such as solar cells. Faced with the search for renewable energy sources and sustainable technologies, the application of this natural pigment has been gaining prominence.
  • 99
  • 11 Dec 2023
Topic Review
Small-Molecule Thermoresponsive Ionic Liquid Materials
Ionic liquids (ILs) are a class of low-melting molten salts (<100 °C) constituted entirely of ions, and their research has gained tremendous attention in line with their remarkably growing applications.
  • 99
  • 07 Dec 2023
Topic Review
Synthesis of S-α-(Acyloxy)alkyl Xanthates
α-(Acyloxy)alkyl radicals of general structure 1 are key intermediates in the polymerization of vinyl esters 2, especially vinyl acetate (2, R = Me); however, their use in the synthesis of small molecules has remained underdeveloped.
  • 116
  • 01 Dec 2023
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