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Topic Review
Stabilization of Hexa-Histidine-Containing Organophosphorus Hydrolase
Organophosphorus hydrolase, containing a genetically introduced hexahistidine sequence (His6-OPH) can hydrolyze various  substrates, such as  organophosphorus pesticides and chemical warfare agents, mycotoxins, and N-acyl homoserine lactones. The application of various carrier materials (metal-organic frameworks, polypeptides, bacterial cellulose, polyhydroxybutyrate, succinylated gelatin, etc.) for the immobilization and stabilization of His6-OPH by various methods, enables creation of biocatalysts with various properties and potential uses, in particular, as antidotes, recognition elements of biosensors, in fibers with chemical and biological protection, dressings with antimicrobial properties, highly porous sorbents for the degradation of toxicants, including in flow systems, etc. Immobilized variants of His6-OPH are characterized by increased stability, and the hydrolytic process of destruction of many substrates can be carried out in wider temperature and pH ranges than when using a free form of the enzyme. The variation in methods and carriers for the immobilization of His6-OPH makes it possible to create a wide palette of biocatalysts, significantly expanding the boundaries of enzyme use.
  • 401
  • 14 Feb 2023
Topic Review
Oxygen Reduction Reaction Catalysts Derived from Biopolymers
Due to the limited reaction rate of the oxygen reduction reaction (ORR), it is considered as a limiting factor in the performance of fuel cells and metal-air batteries. Platinum is considered the benchmark catalyst for ORR; however, the scarcity of platinum, its high price, the drift phenomenon, its insufficient durability, and its susceptibility to gas poisoning are the reasons for the constant search for new ORR catalysts. Carbon-based catalysts show exceptional promise in this respect considering economic profitability and activity, and, in addition, they have favorable conductivity and often a large specific surface area.
  • 422
  • 13 Feb 2023
Topic Review
Electrochemical Aptasensors for Detection of Neurodegenerative Diseases Biomarkers
Neurodegenerative diseases (NDs) are becoming a major global health problem. They constitute an incurable diverse group of disorders characterized by the progressive degeneration of the structure and function of the central or peripheral nervous system. There is an enormous unmet demand worldwide for methods for the early detection of ND biomarkers. Among the various approaches reported so far, biosensors are powerful analytical implements that have been applied to detect biomarkers of NDs. Electrochemical aptasensors have been at the forefront of this development not only thanks to their low cost and simple design but also due to advances in nanomaterials modifying the surface of the transducers involved.
  • 512
  • 13 Feb 2023
Topic Review
Metallic Nanoparticles Applications and Therapies
Metallic-based nanoparticles present a unique set of physicochemical properties that support their application in different fields, such as electronics, medical diagnostics, and therapeutics. Particularly, in cancer therapy, the plasmonic resonance, magnetic behavior, X-ray attenuation, and radical oxygen species generation capacity displayed by metallic nanoparticles make them highly promising theragnostic solutions.
  • 400
  • 13 Feb 2023
Topic Review
Metal Nanoclusters Synthesized in Alkaline Ethylene Glycol
The “unprotected” metal and alloy nanoclusters (UMCs) prepared by the alkaline ethylene glycol method, which are stabilized with simple ions and solvent molecules, have the advantages of a small particle size, a narrow size distribution, good stability, highly efficient preparation, easy separation, surface modification and transfer between different phases. They can be composited with diverse materials to prepare catalytic systems with controllable structures, providing an effective means of studying the different factors’ effects on the catalytic properties separately. UMCs have been widely used in the development of high-performance catalysts for a variety of functional systems.
  • 452
  • 13 Feb 2023
Topic Review
Design and Synthesis of Sidechain Phosphorus-Containing Polyacids
Macromolecules containing acidic fragments in side-groups—polyacids—occupy a special place among synthetic polymers. Properties and applications of polyacids are directly related to the chemical structure of macromolecules: the nature of the acidic groups, polymer backbone, and spacers between the main chain and acidic groups. The chemical nature of the phosphorus results in the diversity of acidic >P(O)OH fragments in sidechain phosphorus-containing polyacids (PCPAs) that can be derivatives of phosphoric or phosphinic acids.
  • 579
  • 13 Feb 2023
Topic Review
Improvement of Energy Storage in Phase Change Materials
Utilizing phase change materials (PCMs) is one of the most effective methods of storing thermal energy and is gaining popularity in renewable energy systems. In order to analyze PCM performance, various numerical methods have been deployed to study the transient behaviour during phase changes. PCMs’ low thermal conductivity prevents their use as pure PCMs in industrial applications. There are various efficient methods of enhancing PCM thermal conductivity.
  • 629
  • 13 Feb 2023
Topic Review
Bioactive Compounds from Fruit Crop Wastes
The food industry as a whole is one of the main contributors for food losses and waste generation. To deal with such wastes, research and efforts have been made for the development and valorization of bioactive compounds present in food wastes such as leaves, peels, seeds, and pulp.
  • 559
  • 10 Feb 2023
Topic Review
All-d-Metal Heusler Alloys
A promising strategy, resulting in novel compounds with better mechanical properties and substantial magnetocaloric effects, is favoring the d–d hybridization with transition-metal elements to replace p–d hybridization. The term given to these materials is “all-d-metal”. 
  • 565
  • 10 Feb 2023
Topic Review
Thermal Conductivity Techniques
Conventional thermal fluids have found limited application owing to low thermal conductivity (TC). The need for more efficient fluids has become apparent leading to the development of nanofluids as advanced thermal fluids. Nanofluid synthesis by suspending nano-size materials into conventional thermal fluids to improve thermal properties has been extensively studied. TC is a pivotal property to the utilization of nanofluids in various applications as it is strongly related to improved efficiency and thermal performance. Numerous studies have been conducted on the TC of nanofluids using diverse nanoparticles and base fluids. 
  • 470
  • 10 Feb 2023
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