| Version | Summary | Created by | Modification | Content Size | Created at | Operation |
|---|---|---|---|---|---|---|
| 1 | Jack Zhong | -- | 269 | 2026-09-22 04:49:14 | | | |
| 2 | Catherine Yang | -9 word(s) | 260 | 2026-09-22 05:46:43 | | |
Cellulose nanocrystal is a rod-like crystalline nanoparticle obtained from cellulose, typically 3-20 nm in width and 100-500 nm in length, in which the chains are packed in a crystalline allomorph whose form depends on the source material and the hydrolysis route [1]. It is produced by hydrolysing native cellulose with mineral acid, most commonly sulfuric acid, which also esterifies part of the surface with sulfate half-esters and gives the particle a negative surface charge that stabilises aqueous suspensions [2]. The particles have a high aspect ratio, a density near 1.6 g cm-3, a Young's modulus on the order of 100-150 GPa and a low coefficient of thermal expansion, so they serve as a reinforcing nanofiller in polymers, films and hydrogels [3]. Above a critical concentration in water they self-assemble into a chiral nematic liquid crystal, and drying this phase leaves an iridescent film whose colour depends on the pitch and on the ionic strength of the medium [1]. The surface chemistry can be modified by oxidation, esterification or grafting to adjust compatibility with a given matrix, and carboxylated grades are prepared by TEMPO-mediated oxidation [4]. Limiting factors are the cost of the sulfuric-acid route and the sulfate-induced thermal instability it leaves behind, which restricts melt processing, together with the difficulty of drying the particles without irreversible aggregation [2]. Reported mechanical reinforcement depends on dispersion quality, and aggregation during drying or processing usually reduces the gain; the choice of polymorph has also been shown to affect processability and the properties of the resulting composite [5].