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Zhong, J. Cellulose Nanocrystal. Encyclopedia. Available online: https://encyclopedia.pub/entry/60203 (accessed on 07 October 2026).
Zhong J. Cellulose Nanocrystal. Encyclopedia. Available at: https://encyclopedia.pub/entry/60203. Accessed October 07, 2026.
Zhong, Jack. "Cellulose Nanocrystal" Encyclopedia, https://encyclopedia.pub/entry/60203 (accessed October 07, 2026).
Zhong, J. (2026, September 22). Cellulose Nanocrystal. In Encyclopedia. https://encyclopedia.pub/entry/60203
Zhong, Jack. "Cellulose Nanocrystal." Encyclopedia. Web. 22 September, 2026.
Cellulose Nanocrystal
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Cellulose nanocrystal is a rod-like crystalline nanoparticle obtained from cellulose, typically 3-20 nm in width and 100-500 nm in length, in which the chains are packed in a crystalline allomorph whose form depends on the source material and the hydrolysis route [1]. It is produced by hydrolysing native cellulose with mineral acid, most commonly sulfuric acid, which also esterifies part of the surface with sulfate half-esters and gives the particle a negative surface charge that stabilises aqueous suspensions [2]. The particles have a high aspect ratio, a density near 1.6 g cm-3, a Young's modulus on the order of 100-150 GPa and a low coefficient of thermal expansion, so they serve as a reinforcing nanofiller in polymers, films and hydrogels [3]. Above a critical concentration in water they self-assemble into a chiral nematic liquid crystal, and drying this phase leaves an iridescent film whose colour depends on the pitch and on the ionic strength of the medium [1]. The surface chemistry can be modified by oxidation, esterification or grafting to adjust compatibility with a given matrix, and carboxylated grades are prepared by TEMPO-mediated oxidation [4]. Limiting factors are the cost of the sulfuric-acid route and the sulfate-induced thermal instability it leaves behind, which restricts melt processing, together with the difficulty of drying the particles without irreversible aggregation [2]. Reported mechanical reinforcement depends on dispersion quality, and aggregation during drying or processing usually reduces the gain; the choice of polymorph has also been shown to affect processability and the properties of the resulting composite [5].

nanocellulose sulfuric acid hydrolysis chiral nematic ordering nanocomposite surface functionalization aspect ratio biorenewable material

References

  1. Habibi, Y.; Lucia, L.A.; Rojas, O.J. Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications. Chemical Reviews 2010, 110, 3479-3500. [CrossRef]
  2. Klemm, D.; Kramer, F.; Moritz, S.; Lindstrom, T.; Ankerfors, M.; Gray, D.; Dorris, A. Nanocelluloses: A New Family of Nature-Based Materials. Angewandte Chemie International Edition 2011, 50, 5438-5466. [CrossRef]
  3. Raza, M.; Abu-Jdayil, B. Cellulose nanocrystals from lignocellulosic feedstock: a review of production technology and surface chemistry modification. Cellulose 2022, 29, 685-722. [CrossRef]
  4. Lam, E.; Hemraz, U.D. Preparation and Surface Functionalization of Carboxylated Cellulose Nanocrystals. Nanomaterials 2021, 11, 1641. [CrossRef]
  5. Chen, T.; Li, J.; Xu, J.; Gao, Y.; Zhu, S.; Wang, B.; Ying, G. Effect of Acetylation of Two Cellulose Nanocrystal Polymorphs on Processibility and Physical Properties of Polylactide/Cellulose Nanocrystal Composite Film. Molecules 2023, 28, 4667. [CrossRef]
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Subjects: Polymer Science
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Update Date: 22 Sep 2026
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